Inclusion compounds : structure, reactivity and selectivity

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dc.contributor.advisorNassimbeni, Luigi Ren_ZA
dc.contributor.authorSu, Hongen_ZA
dc.date.accessioned2014-11-22T05:52:53Z
dc.date.available2014-11-22T05:52:53Z
dc.date.issued2002en_ZA
dc.descriptionIncludes bibliographical references.en_ZA
dc.description.abstractThis thesis is concerned with structure, thermodynamic and kinetic aspects of a variety of inclusion compounds which contain small organic guests. The host compounds studied are alkaline-earth metal salts of O,O’-dibenzoyl-(2R, 3R)-tartraric acid (magnesium, calcium and strontium), 1,1’-bis-(4-hydroxyphenyl)cyclohexane (DHPC) and 2,2’-dihydroxy-1,1’-binaphthyl (BINAP). The alkaline-earth metal salts form coordination complexes with 2-methoxyethanol, water or ethanol and the guests act as a part of the coordination sphere of the metal ions. The diol host DHPC preferably forms layer type inclusion compounds with the isomers of picoline, lutidine and xylidine, as well as a number of selected solvents including 1,4-dioxane, DMSO, morpholine, THF and acetone, preferably in channel type inclusion modes. In the latter two classes of inclusion compounds the inclusion is facilitated by the formation of hydrogen bonds from the host hydroxyl moieties to the guests.en_ZA
dc.identifier.apacitationSu, H. (2002). <i>Inclusion compounds : structure, reactivity and selectivity</i>. (Thesis). University of Cape Town ,Faculty of Science ,Department of Chemistry. Retrieved from http://hdl.handle.net/11427/9783en_ZA
dc.identifier.chicagocitationSu, Hong. <i>"Inclusion compounds : structure, reactivity and selectivity."</i> Thesis., University of Cape Town ,Faculty of Science ,Department of Chemistry, 2002. http://hdl.handle.net/11427/9783en_ZA
dc.identifier.citationSu, H. 2002. Inclusion compounds : structure, reactivity and selectivity. University of Cape Town.en_ZA
dc.identifier.ris TY - Thesis / Dissertation AU - Su, Hong AB - This thesis is concerned with structure, thermodynamic and kinetic aspects of a variety of inclusion compounds which contain small organic guests. The host compounds studied are alkaline-earth metal salts of O,O’-dibenzoyl-(2R, 3R)-tartraric acid (magnesium, calcium and strontium), 1,1’-bis-(4-hydroxyphenyl)cyclohexane (DHPC) and 2,2’-dihydroxy-1,1’-binaphthyl (BINAP). The alkaline-earth metal salts form coordination complexes with 2-methoxyethanol, water or ethanol and the guests act as a part of the coordination sphere of the metal ions. The diol host DHPC preferably forms layer type inclusion compounds with the isomers of picoline, lutidine and xylidine, as well as a number of selected solvents including 1,4-dioxane, DMSO, morpholine, THF and acetone, preferably in channel type inclusion modes. In the latter two classes of inclusion compounds the inclusion is facilitated by the formation of hydrogen bonds from the host hydroxyl moieties to the guests. DA - 2002 DB - OpenUCT DP - University of Cape Town LK - https://open.uct.ac.za PB - University of Cape Town PY - 2002 T1 - Inclusion compounds : structure, reactivity and selectivity TI - Inclusion compounds : structure, reactivity and selectivity UR - http://hdl.handle.net/11427/9783 ER - en_ZA
dc.identifier.urihttp://hdl.handle.net/11427/9783
dc.identifier.vancouvercitationSu H. Inclusion compounds : structure, reactivity and selectivity. [Thesis]. University of Cape Town ,Faculty of Science ,Department of Chemistry, 2002 [cited yyyy month dd]. Available from: http://hdl.handle.net/11427/9783en_ZA
dc.language.isoengen_ZA
dc.publisher.departmentDepartment of Chemistryen_ZA
dc.publisher.facultyFaculty of Scienceen_ZA
dc.publisher.institutionUniversity of Cape Town
dc.subject.otherChemistryen_ZA
dc.titleInclusion compounds : structure, reactivity and selectivityen_ZA
dc.typeDoctoral Thesis
dc.type.qualificationlevelDoctoral
dc.type.qualificationnamePhDen_ZA
uct.type.filetypeText
uct.type.filetypeImage
uct.type.publicationResearchen_ZA
uct.type.resourceThesisen_ZA
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