Micromechanical modelling of advanced hierarchical composites

dc.contributor.advisorReddy, Batmanathan
dc.contributor.advisorBargmann, Swantje
dc.contributor.authorGriffiths, Emma
dc.date.accessioned2020-09-11T11:36:57Z
dc.date.available2020-09-11T11:36:57Z
dc.date.issued2020
dc.date.updated2020-09-11T11:35:56Z
dc.description.abstractNanoporous metals are uniquely interesting materials. Their high ductility and impressive strength in compression make them a favourable candidate for use in structural applications. However, these materials under-perform when tested in tension. This issue may be addressed by impregnating the nanoporous metal with a polymer. In this work the behaviour of a polymer impregnated nanoporous gold (NPG) composite is explored using the finite element method in three different scenarios: linear elasticity, fracture and electrically stimulated actuation. Using representative volume elements (RVEs), previously unexplored relationships between the macroscopic material response and its microstructure as well as interesting mechanisms and deformation strategies are explored. Firstly the homogenization and micromechanical response under compression of a gold/epoxy nanocomposite is investigated. Investigation into the stress-strain response within the material reveals a complex interaction between the constituents resulting in both compressive and tensile strains. With specific focus on the loading modes of the individual ligaments, significant axial and bending loading as well as an unexpectedly large amount of shear stress is seen. Following this the improved ductility and resistance to fracture of a gold/polymer nanocomposite compared to the pure NPG material is revealed using computational compact-tension tests. It is observed that the polymer stabilizes the gold thus preventing ductile fracture. Several toughening mechanisms are also revealed. Previously unexplored effects of increasing the volume fraction on the ductility and strength of the composite are also explored. The functionality of the gold/polymer nanocomposite as an actuator material is then investigated. A coupled chemo-electro-mechanical material model is adopted to model the electrically stimulated deformation. This is carried out in Abaqus using a novel staggered explicit-implicit solution scheme. Simulation of several RVEs with different gold volume fractions show that while the gold provides strength and support, increasing its volume fraction hinders both the ion transport speed and the total deformation of the nanocomposite. A complex interaction between the stress response and the gold volume fraction is also observed.
dc.identifier.apacitationGriffiths, E. (2020). <i>Micromechanical modelling of advanced hierarchical composites</i>. (). ,Engineering and the Built Environment ,Department of Mechanical Engineering. Retrieved from http://hdl.handle.net/11427/32222en_ZA
dc.identifier.chicagocitationGriffiths, Emma. <i>"Micromechanical modelling of advanced hierarchical composites."</i> ., ,Engineering and the Built Environment ,Department of Mechanical Engineering, 2020. http://hdl.handle.net/11427/32222en_ZA
dc.identifier.citationGriffiths, E. 2020. Micromechanical modelling of advanced hierarchical composites. . ,Engineering and the Built Environment ,Department of Mechanical Engineering. http://hdl.handle.net/11427/32222en_ZA
dc.identifier.ris TY - Doctoral Thesis AU - Griffiths, Emma AB - Nanoporous metals are uniquely interesting materials. Their high ductility and impressive strength in compression make them a favourable candidate for use in structural applications. However, these materials under-perform when tested in tension. This issue may be addressed by impregnating the nanoporous metal with a polymer. In this work the behaviour of a polymer impregnated nanoporous gold (NPG) composite is explored using the finite element method in three different scenarios: linear elasticity, fracture and electrically stimulated actuation. Using representative volume elements (RVEs), previously unexplored relationships between the macroscopic material response and its microstructure as well as interesting mechanisms and deformation strategies are explored. Firstly the homogenization and micromechanical response under compression of a gold/epoxy nanocomposite is investigated. Investigation into the stress-strain response within the material reveals a complex interaction between the constituents resulting in both compressive and tensile strains. With specific focus on the loading modes of the individual ligaments, significant axial and bending loading as well as an unexpectedly large amount of shear stress is seen. Following this the improved ductility and resistance to fracture of a gold/polymer nanocomposite compared to the pure NPG material is revealed using computational compact-tension tests. It is observed that the polymer stabilizes the gold thus preventing ductile fracture. Several toughening mechanisms are also revealed. Previously unexplored effects of increasing the volume fraction on the ductility and strength of the composite are also explored. The functionality of the gold/polymer nanocomposite as an actuator material is then investigated. A coupled chemo-electro-mechanical material model is adopted to model the electrically stimulated deformation. This is carried out in Abaqus using a novel staggered explicit-implicit solution scheme. Simulation of several RVEs with different gold volume fractions show that while the gold provides strength and support, increasing its volume fraction hinders both the ion transport speed and the total deformation of the nanocomposite. A complex interaction between the stress response and the gold volume fraction is also observed. DA - 2020_ DB - OpenUCT DP - University of Cape Town KW - Mechanical Engineering LK - https://open.uct.ac.za PY - 2020 T1 - Micromechanical modelling of advanced hierarchical composites TI - Micromechanical modelling of advanced hierarchical composites UR - http://hdl.handle.net/11427/32222 ER - en_ZA
dc.identifier.urihttp://hdl.handle.net/11427/32222
dc.identifier.vancouvercitationGriffiths E. Micromechanical modelling of advanced hierarchical composites. []. ,Engineering and the Built Environment ,Department of Mechanical Engineering, 2020 [cited yyyy month dd]. Available from: http://hdl.handle.net/11427/32222en_ZA
dc.language.rfc3066eng
dc.publisher.departmentDepartment of Mechanical Engineering
dc.publisher.facultyFaculty of Engineering and the Built Environment
dc.subjectMechanical Engineering
dc.titleMicromechanical modelling of advanced hierarchical composites
dc.typeDoctoral Thesis
dc.type.qualificationlevelDoctoral
dc.type.qualificationlevelPhD
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