Aqueous phase catalysis using mono- and bimetallic transition metal complexes

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dc.contributor.advisorSmith, Gregory Sen_ZA
dc.contributor.advisorMapolie, Selwyn Fen_ZA
dc.contributor.advisorVenter, Gerhard Aen_ZA
dc.contributor.authorMatsinha, Leah Charlieen_ZA
dc.date.accessioned2016-02-02T14:43:55Z
dc.date.available2016-02-02T14:43:55Z
dc.date.issued2015en_ZA
dc.descriptionIncludes bibliographical referencesen_ZA
dc.description.abstractThe synthesis and characterization of monomeric and dimeric salicylaldimine water-soluble ligands is discussed. The salicylaldimine ligands (2.3-2.10) were synthesised via Schiff base condensation reactions of various amines with water-soluble sulfonated salicylaldehydes (2.1 and 2.2). The ligands were characterized using various analytical and spectroscopic techniques. Complexation reactions of these water-soluble ligands (2.3-2.10) with [Rh(COD)Cl]2 gave the corresponding water-soluble mononuclear (2.11-2.14) and binuclear (2.15-2.18) Rh(I) complexes. All the complexes were characterized using nuclear magnetic resonance spectroscopy, infrared spectroscopy, single crystal X-ray diffraction (for complex 2.14), mass spectrometry, elemental analysis and melting point determinations.en_ZA
dc.identifier.apacitationMatsinha, L. C. (2015). <i>Aqueous phase catalysis using mono- and bimetallic transition metal complexes</i>. (Thesis). University of Cape Town ,Faculty of Science ,Department of Chemistry. Retrieved from http://hdl.handle.net/11427/16704en_ZA
dc.identifier.chicagocitationMatsinha, Leah Charlie. <i>"Aqueous phase catalysis using mono- and bimetallic transition metal complexes."</i> Thesis., University of Cape Town ,Faculty of Science ,Department of Chemistry, 2015. http://hdl.handle.net/11427/16704en_ZA
dc.identifier.citationMatsinha, L. 2015. Aqueous phase catalysis using mono- and bimetallic transition metal complexes. University of Cape Town.en_ZA
dc.identifier.ris TY - Thesis / Dissertation AU - Matsinha, Leah Charlie AB - The synthesis and characterization of monomeric and dimeric salicylaldimine water-soluble ligands is discussed. The salicylaldimine ligands (2.3-2.10) were synthesised via Schiff base condensation reactions of various amines with water-soluble sulfonated salicylaldehydes (2.1 and 2.2). The ligands were characterized using various analytical and spectroscopic techniques. Complexation reactions of these water-soluble ligands (2.3-2.10) with [Rh(COD)Cl]2 gave the corresponding water-soluble mononuclear (2.11-2.14) and binuclear (2.15-2.18) Rh(I) complexes. All the complexes were characterized using nuclear magnetic resonance spectroscopy, infrared spectroscopy, single crystal X-ray diffraction (for complex 2.14), mass spectrometry, elemental analysis and melting point determinations. DA - 2015 DB - OpenUCT DP - University of Cape Town LK - https://open.uct.ac.za PB - University of Cape Town PY - 2015 T1 - Aqueous phase catalysis using mono- and bimetallic transition metal complexes TI - Aqueous phase catalysis using mono- and bimetallic transition metal complexes UR - http://hdl.handle.net/11427/16704 ER - en_ZA
dc.identifier.urihttp://hdl.handle.net/11427/16704
dc.identifier.vancouvercitationMatsinha LC. Aqueous phase catalysis using mono- and bimetallic transition metal complexes. [Thesis]. University of Cape Town ,Faculty of Science ,Department of Chemistry, 2015 [cited yyyy month dd]. Available from: http://hdl.handle.net/11427/16704en_ZA
dc.language.isoengen_ZA
dc.publisher.departmentDepartment of Chemistryen_ZA
dc.publisher.facultyFaculty of Scienceen_ZA
dc.publisher.institutionUniversity of Cape Town
dc.subject.otherChemistryen_ZA
dc.titleAqueous phase catalysis using mono- and bimetallic transition metal complexesen_ZA
dc.typeDoctoral Thesis
dc.type.qualificationlevelDoctoral
dc.type.qualificationnamePhDen_ZA
uct.type.filetypeText
uct.type.filetypeImage
uct.type.publicationResearchen_ZA
uct.type.resourceThesisen_ZA
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