Aromatic hydroxylations over titanium-substituted crystalline silicates

dc.contributor.advisorvan Steen, Eric
dc.contributor.advisorGammon, David
dc.contributor.authorWilkenhöner, Uwe
dc.date.accessioned2023-09-08T11:44:13Z
dc.date.available2023-09-08T11:44:13Z
dc.date.issued2001
dc.date.updated2023-09-07T11:15:48Z
dc.description.abstractThis work focuses on aromatic hydroxylations over titanium-substituted zeolites of different pore sizes (TS-1, Al-free Ti-beta and Ti-HMS) using aqueous H2O2 as the oxidant. The aim was to gain a deeper understanding of the key factors controlling activity and selectivity, which implied an investigation of the reaction kinetics and the adsorption and diffusion properties of reactants and products in the various catalysts using different solvents. The role of shape selectivity inside the micropores of the solids and the reaction at their external surface was also examined.
dc.identifier.apacitationWilkenhöner, U. (2001). <i>Aromatic hydroxylations over titanium-substituted crystalline silicates</i>. (). ,Faculty of Engineering and the Built Environment ,Department of Chemical Engineering. Retrieved from http://hdl.handle.net/11427/38467en_ZA
dc.identifier.chicagocitationWilkenhöner, Uwe. <i>"Aromatic hydroxylations over titanium-substituted crystalline silicates."</i> ., ,Faculty of Engineering and the Built Environment ,Department of Chemical Engineering, 2001. http://hdl.handle.net/11427/38467en_ZA
dc.identifier.citationWilkenhöner, U. 2001. Aromatic hydroxylations over titanium-substituted crystalline silicates. . ,Faculty of Engineering and the Built Environment ,Department of Chemical Engineering. http://hdl.handle.net/11427/38467en_ZA
dc.identifier.risTY - Doctoral Thesis AU - Wilkenhöner, Uwe AB - This work focuses on aromatic hydroxylations over titanium-substituted zeolites of different pore sizes (TS-1, Al-free Ti-beta and Ti-HMS) using aqueous H2O2 as the oxidant. The aim was to gain a deeper understanding of the key factors controlling activity and selectivity, which implied an investigation of the reaction kinetics and the adsorption and diffusion properties of reactants and products in the various catalysts using different solvents. The role of shape selectivity inside the micropores of the solids and the reaction at their external surface was also examined. DA - 2001_ DB - OpenUCT DP - University of Cape Town KW - chemical engineering LK - https://open.uct.ac.za PY - 2001 T1 - ETD: Aromatic hydroxylations over titanium-substituted crystalline silicates TI - ETD: Aromatic hydroxylations over titanium-substituted crystalline silicates UR - http://hdl.handle.net/11427/38467 ER -en_ZA
dc.identifier.urihttp://hdl.handle.net/11427/38467
dc.identifier.vancouvercitationWilkenhöner U. Aromatic hydroxylations over titanium-substituted crystalline silicates. []. ,Faculty of Engineering and the Built Environment ,Department of Chemical Engineering, 2001 [cited yyyy month dd]. Available from: http://hdl.handle.net/11427/38467en_ZA
dc.language.rfc3066eng
dc.publisher.departmentDepartment of Chemical Engineering
dc.publisher.facultyFaculty of Engineering and the Built Environment
dc.subjectchemical engineering
dc.titleAromatic hydroxylations over titanium-substituted crystalline silicates
dc.typeDoctoral Thesis
dc.type.qualificationlevelDoctoral
dc.type.qualificationlevelPhD
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