Application of crystal field theory to the infrared spectra of transition metal complexes

Shephard, Gordon Seymour

Application of crystal field theory to the infrared spectra of transition metal complexes

Thesis / Dissertation

1973

Abstract

[pages missing] problem in the IR spectra of 8-quinolinol chelqtes of di~ and trivalent metals of the first transition series. The metal-sensitivity of bands in the IR spectra of structura~ly differing substituted 8-quinolinol Qhelates ~eceives an interpretation in terms of crystal field theory. The effect of halogen and methyl substituents in the I~ spectra of the Cu(II) chelates is consistent with the band assignments based on crystal field effects P.nd is relat;.ep to both the resonance and inductive capacities of th~ substituents. A total of 232 compounds have been synthesized and are discussed.

Keywords

Chemistry

Reference:

Collections

PhD / Doctoral

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