The design, synthesis and characterization of polynuclear materials for applications for catalysis

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dc.contributor.advisorSmith, Gregory Sen_ZA
dc.contributor.advisorJardine, Anwaren_ZA
dc.contributor.authorMakhubela, Banothile Charity Eventsen_ZA
dc.date.accessioned2015-01-05T18:57:44Z
dc.date.available2015-01-05T18:57:44Z
dc.date.issued2012en_ZA
dc.descriptionIncludes abstract.en_ZA
dc.descriptionIncludes bibliographical references.en_ZA
dc.description.abstractThe synthesis and characterization of new chitosan- and 6-deoxy-6-amino chitosan-supported ligands is discussed. This was achieved via the reaction of either 2-pyridinecarboxaldehyde or 2-(diphenylphosphino)benzaldehyde with the accessible amino groups of chitosan to afford chitosan-supported Schiff base ligands (2.1-2.4) bearing iminopyridyl and iminophosphine functionalities on the surface. Complexation reactions with [PdCl2(COD)] and [RhCl(CO)2]2 gave the corresponding chitosan-supported complexes (2.5-2.8) and (2.13-2.14). These metal-containing materials and their precursors were isolated as air and moisture stable solids which proved insoluble in common organic solvents and have been characterized analytically and spectroscopically...en_ZA
dc.identifier.apacitationMakhubela, B. C. E. (2012). <i>The design, synthesis and characterization of polynuclear materials for applications for catalysis</i>. (Thesis). University of Cape Town ,Faculty of Science ,Department of Chemistry. Retrieved from http://hdl.handle.net/11427/11505en_ZA
dc.identifier.chicagocitationMakhubela, Banothile Charity Events. <i>"The design, synthesis and characterization of polynuclear materials for applications for catalysis."</i> Thesis., University of Cape Town ,Faculty of Science ,Department of Chemistry, 2012. http://hdl.handle.net/11427/11505en_ZA
dc.identifier.citationMakhubela, B. 2012. The design, synthesis and characterization of polynuclear materials for applications for catalysis. University of Cape Town.en_ZA
dc.identifier.ris TY - Thesis / Dissertation AU - Makhubela, Banothile Charity Events AB - The synthesis and characterization of new chitosan- and 6-deoxy-6-amino chitosan-supported ligands is discussed. This was achieved via the reaction of either 2-pyridinecarboxaldehyde or 2-(diphenylphosphino)benzaldehyde with the accessible amino groups of chitosan to afford chitosan-supported Schiff base ligands (2.1-2.4) bearing iminopyridyl and iminophosphine functionalities on the surface. Complexation reactions with [PdCl2(COD)] and [RhCl(CO)2]2 gave the corresponding chitosan-supported complexes (2.5-2.8) and (2.13-2.14). These metal-containing materials and their precursors were isolated as air and moisture stable solids which proved insoluble in common organic solvents and have been characterized analytically and spectroscopically... DA - 2012 DB - OpenUCT DP - University of Cape Town LK - https://open.uct.ac.za PB - University of Cape Town PY - 2012 T1 - The design, synthesis and characterization of polynuclear materials for applications for catalysis TI - The design, synthesis and characterization of polynuclear materials for applications for catalysis UR - http://hdl.handle.net/11427/11505 ER - en_ZA
dc.identifier.urihttp://hdl.handle.net/11427/11505
dc.identifier.vancouvercitationMakhubela BCE. The design, synthesis and characterization of polynuclear materials for applications for catalysis. [Thesis]. University of Cape Town ,Faculty of Science ,Department of Chemistry, 2012 [cited yyyy month dd]. Available from: http://hdl.handle.net/11427/11505en_ZA
dc.language.isoengen_ZA
dc.publisher.departmentDepartment of Chemistryen_ZA
dc.publisher.facultyFaculty of Scienceen_ZA
dc.publisher.institutionUniversity of Cape Town
dc.subject.otherChemistryen_ZA
dc.titleThe design, synthesis and characterization of polynuclear materials for applications for catalysisen_ZA
dc.typeDoctoral Thesis
dc.type.qualificationlevelDoctoral
dc.type.qualificationnamePhDen_ZA
uct.type.filetypeText
uct.type.filetypeImage
uct.type.publicationResearchen_ZA
uct.type.resourceThesisen_ZA
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