Synthesis of N-alkyl-and N,N-dialkyl-N'-acyl- and N'-aroythioureas, and aspects of their co-ordination chemistry with Pt(II)and Pd(II)

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dc.contributor.advisorKoch, Klausen_ZA
dc.contributor.authorMiller, Jörn Derrick Schusteren_ZA
dc.date.accessioned2014-08-13T14:27:14Z
dc.date.available2014-08-13T14:27:14Z
dc.date.issued2000en_ZA
dc.descriptionIncludes bibliographical references.en_ZA
dc.description.abstractThe synthesis of simple, and also bipodal N-substituted N'-acyl- and N'-aroylthiourea ligands has been investigated, along with aspects of their co-ordination chemistry to Pt(II) and Pd(II). The ligands are commonly produced by reacting a secondary or primary amine with an acyl or aroyl isothiocyanate. This synthesis requires nucleophilic addition of the amine to the thiocarbonyl carbon of the acyl or aroyl isothocyanate. However, a competitive side-reaction frequently occurs because the amine nucleophile can attack the carbonyl carbon of the isothiocyanate reagent instead. This leads to substitution of the isothiocyanate moiety and the formation of an N-substituted amide.en_ZA
dc.identifier.apacitationMiller, J. D. S. (2000). <i>Synthesis of N-alkyl-and N,N-dialkyl-N'-acyl- and N'-aroythioureas, and aspects of their co-ordination chemistry with Pt(II)and Pd(II)</i>. (Thesis). University of Cape Town ,Faculty of Science ,Department of Chemistry. Retrieved from http://hdl.handle.net/11427/6336en_ZA
dc.identifier.chicagocitationMiller, Jörn Derrick Schuster. <i>"Synthesis of N-alkyl-and N,N-dialkyl-N'-acyl- and N'-aroythioureas, and aspects of their co-ordination chemistry with Pt(II)and Pd(II)."</i> Thesis., University of Cape Town ,Faculty of Science ,Department of Chemistry, 2000. http://hdl.handle.net/11427/6336en_ZA
dc.identifier.citationMiller, J. 2000. Synthesis of N-alkyl-and N,N-dialkyl-N'-acyl- and N'-aroythioureas, and aspects of their co-ordination chemistry with Pt(II)and Pd(II). University of Cape Town.en_ZA
dc.identifier.ris TY - Thesis / Dissertation AU - Miller, Jörn Derrick Schuster AB - The synthesis of simple, and also bipodal N-substituted N'-acyl- and N'-aroylthiourea ligands has been investigated, along with aspects of their co-ordination chemistry to Pt(II) and Pd(II). The ligands are commonly produced by reacting a secondary or primary amine with an acyl or aroyl isothiocyanate. This synthesis requires nucleophilic addition of the amine to the thiocarbonyl carbon of the acyl or aroyl isothocyanate. However, a competitive side-reaction frequently occurs because the amine nucleophile can attack the carbonyl carbon of the isothiocyanate reagent instead. This leads to substitution of the isothiocyanate moiety and the formation of an N-substituted amide. DA - 2000 DB - OpenUCT DP - University of Cape Town LK - https://open.uct.ac.za PB - University of Cape Town PY - 2000 T1 - Synthesis of N-alkyl-and N,N-dialkyl-N'-acyl- and N'-aroythioureas, and aspects of their co-ordination chemistry with Pt(II)and Pd(II) TI - Synthesis of N-alkyl-and N,N-dialkyl-N'-acyl- and N'-aroythioureas, and aspects of their co-ordination chemistry with Pt(II)and Pd(II) UR - http://hdl.handle.net/11427/6336 ER - en_ZA
dc.identifier.urihttp://hdl.handle.net/11427/6336
dc.identifier.vancouvercitationMiller JDS. Synthesis of N-alkyl-and N,N-dialkyl-N'-acyl- and N'-aroythioureas, and aspects of their co-ordination chemistry with Pt(II)and Pd(II). [Thesis]. University of Cape Town ,Faculty of Science ,Department of Chemistry, 2000 [cited yyyy month dd]. Available from: http://hdl.handle.net/11427/6336en_ZA
dc.language.isoengen_ZA
dc.publisher.departmentDepartment of Chemistryen_ZA
dc.publisher.facultyFaculty of Scienceen_ZA
dc.publisher.institutionUniversity of Cape Town
dc.subject.otherChemistryen_ZA
dc.titleSynthesis of N-alkyl-and N,N-dialkyl-N'-acyl- and N'-aroythioureas, and aspects of their co-ordination chemistry with Pt(II)and Pd(II)en_ZA
dc.typeDoctoral Thesis
dc.type.qualificationlevelDoctoral
dc.type.qualificationnamePhDen_ZA
uct.type.filetypeText
uct.type.filetypeImage
uct.type.publicationResearchen_ZA
uct.type.resourceThesisen_ZA
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