Progressive design and self-assembly of supramolecular architectures : based on metallamacrocyclic nickel(II) complexes with bipodal tetra-alkylaroylbis (thioureas)

Simple item page
dc.contributor.advisorBourne, Susan Aen_ZA
dc.contributor.advisorKoch, Klausen_ZA
dc.contributor.authorHallale, Orenen_ZA
dc.date.accessioned2014-08-13T14:26:24Z
dc.date.available2014-08-13T14:26:24Z
dc.date.issued2004en_ZA
dc.descriptionIncludes bibliographical references.en_ZA
dc.description.abstractRationally designed bipodal3,3,3',3'-tetraalkyl-l,1'-benzoylbis(thioureas) are used as pre-programmed cheiating ligands to form metallamacrocyclic square planar nickel(ll) complexes via self-assembly. Metal : ligand stoichiometries of either 2:2 or 3:3 can be achieved by using meta- or para- substituted ligands. The metallamacrocyclic complexes are subsequently converted into octahedral adducts via the addition of monodentate nitrogen donor ligands. Metallamacrocycles are further employed as secondary building units in the self-assembly of I-dimensional double- or tripleconnected coordination polymers. The synthesis of these polymers is achieved with the use of exo-bidentate nitrogen donor ligands.en_ZA
dc.identifier.apacitationHallale, O. (2004). <i>Progressive design and self-assembly of supramolecular architectures : based on metallamacrocyclic nickel(II) complexes with bipodal tetra-alkylaroylbis (thioureas)</i>. (Thesis). University of Cape Town ,Faculty of Science ,Department of Chemistry. Retrieved from http://hdl.handle.net/11427/6310en_ZA
dc.identifier.chicagocitationHallale, Oren. <i>"Progressive design and self-assembly of supramolecular architectures : based on metallamacrocyclic nickel(II) complexes with bipodal tetra-alkylaroylbis (thioureas)."</i> Thesis., University of Cape Town ,Faculty of Science ,Department of Chemistry, 2004. http://hdl.handle.net/11427/6310en_ZA
dc.identifier.citationHallale, O. 2004. Progressive design and self-assembly of supramolecular architectures : based on metallamacrocyclic nickel(II) complexes with bipodal tetra-alkylaroylbis (thioureas). University of Cape Town.en_ZA
dc.identifier.ris TY - Thesis / Dissertation AU - Hallale, Oren AB - Rationally designed bipodal3,3,3',3'-tetraalkyl-l,1'-benzoylbis(thioureas) are used as pre-programmed cheiating ligands to form metallamacrocyclic square planar nickel(ll) complexes via self-assembly. Metal : ligand stoichiometries of either 2:2 or 3:3 can be achieved by using meta- or para- substituted ligands. The metallamacrocyclic complexes are subsequently converted into octahedral adducts via the addition of monodentate nitrogen donor ligands. Metallamacrocycles are further employed as secondary building units in the self-assembly of I-dimensional double- or tripleconnected coordination polymers. The synthesis of these polymers is achieved with the use of exo-bidentate nitrogen donor ligands. DA - 2004 DB - OpenUCT DP - University of Cape Town LK - https://open.uct.ac.za PB - University of Cape Town PY - 2004 T1 - Progressive design and self-assembly of supramolecular architectures : based on metallamacrocyclic nickel(II) complexes with bipodal tetra-alkylaroylbis (thioureas) TI - Progressive design and self-assembly of supramolecular architectures : based on metallamacrocyclic nickel(II) complexes with bipodal tetra-alkylaroylbis (thioureas) UR - http://hdl.handle.net/11427/6310 ER - en_ZA
dc.identifier.urihttp://hdl.handle.net/11427/6310
dc.identifier.vancouvercitationHallale O. Progressive design and self-assembly of supramolecular architectures : based on metallamacrocyclic nickel(II) complexes with bipodal tetra-alkylaroylbis (thioureas). [Thesis]. University of Cape Town ,Faculty of Science ,Department of Chemistry, 2004 [cited yyyy month dd]. Available from: http://hdl.handle.net/11427/6310en_ZA
dc.language.isoengen_ZA
dc.publisher.departmentDepartment of Chemistryen_ZA
dc.publisher.facultyFaculty of Scienceen_ZA
dc.publisher.institutionUniversity of Cape Town
dc.subject.otherChemistryen_ZA
dc.titleProgressive design and self-assembly of supramolecular architectures : based on metallamacrocyclic nickel(II) complexes with bipodal tetra-alkylaroylbis (thioureas)en_ZA
dc.typeDoctoral Thesis
dc.type.qualificationlevelDoctoral
dc.type.qualificationnamePhDen_ZA
uct.type.filetypeText
uct.type.filetypeImage
uct.type.publicationResearchen_ZA
uct.type.resourceThesisen_ZA
Files
Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
thesis_sci_2004_hallale_o.pdf
Size:
23.39 MB
Format:
Adobe Portable Document Format
Description:
Download
Collections
PhD / Doctoral