Investigating the use of sodium metasilicate to improve the flotation performance of altered PGE ores
| dc.contributor.advisor | Mcfadzean, Belinda | |
| dc.contributor.advisor | Becker Megan | |
| dc.contributor.advisor | Geldenhuys, Stefan | |
| dc.contributor.author | Molifie, Andrea | |
| dc.date.accessioned | 2022-03-03T21:06:05Z | |
| dc.date.available | 2022-03-03T21:06:05Z | |
| dc.date.issued | 2021 | |
| dc.date.updated | 2022-03-03T21:04:21Z | |
| dc.description.abstract | Mineral hydration is known to result in low flotation recoveries and grades within primary platinum group element ores worldwide. This is because the phyllosilicate minerals derived from hydration reactions of silicate minerals (i) form electrostatic coatings on valuable minerals that in turn hinders collector adsorption, (ii) alter the viscosity of the slurry leading to poor gas dispersion and (iii) decrease the concentrate grade due to naturally-floating gangue. Sodium metasilicate was investigated because its dispersant, rheology modifying, and depressant properties could prove promising in combating the problems associated with these ore types. Quantitative evaluation by scanning electron microscopy (QEMSCAN) analysis revealed large quantities of serpentine and talc present within the ore sample used in this study, which led to a poor flotation response, as indicated by batch flotation tests. Using sodium metasilicate improved the recoveries and grades at high dosages (>1000 g/t). A suite of techniques was chosen to decouple sodium metasilicates' effects to answer why an improved flotation performance occurred. The zeta potential experiments indicate that improved recoveries are, in part, as a result of the reversal of serpentines surface charge, creating electrostatic repulsion between serpentine and valuable minerals which prevents the coating of valuable minerals by serpentine slimes. This corresponded with improved recoveries of a PGM proxy in the presence of serpentine slimes and a high sodium metasilicate dosage. Ore dilution and rheology tests indicate that decreased viscosity at high dosages also improved recoveries. This was supported by slower particle settling rates at high sodium metasilicate dosages during particle settling measurements. Talc micro-flotation tests revealed that the depression of talc occurred at higher sodium metasilicate dosages, which improved concentrate grade. This was supported by a QEMSCAN concentrate analysis of the sodium metasilicate batch flotation concentrates, which confirmed that talc, and other associated silicate minerals, were depressed at high sodium metasilicate dosages. The processing of near-surface altered ores is becoming an increasing problem worldwide and the use of sodium metasilicate proved valuable in mitigating the problems associated with the altered ore investigated in this study. | |
| dc.identifier.apacitation | Molifie, A. (2021). <i>Investigating the use of sodium metasilicate to improve the flotation performance of altered PGE ores</i>. (). ,Faculty of Engineering and the Built Environment ,Department of Chemical Engineering. Retrieved from http://hdl.handle.net/11427/35888 | en_ZA |
| dc.identifier.chicagocitation | Molifie, Andrea. <i>"Investigating the use of sodium metasilicate to improve the flotation performance of altered PGE ores."</i> ., ,Faculty of Engineering and the Built Environment ,Department of Chemical Engineering, 2021. http://hdl.handle.net/11427/35888 | en_ZA |
| dc.identifier.citation | Molifie, A. 2021. Investigating the use of sodium metasilicate to improve the flotation performance of altered PGE ores. . ,Faculty of Engineering and the Built Environment ,Department of Chemical Engineering. http://hdl.handle.net/11427/35888 | en_ZA |
| dc.identifier.ris | TY - Doctoral Thesis AU - Molifie, Andrea AB - Mineral hydration is known to result in low flotation recoveries and grades within primary platinum group element ores worldwide. This is because the phyllosilicate minerals derived from hydration reactions of silicate minerals (i) form electrostatic coatings on valuable minerals that in turn hinders collector adsorption, (ii) alter the viscosity of the slurry leading to poor gas dispersion and (iii) decrease the concentrate grade due to naturally-floating gangue. Sodium metasilicate was investigated because its dispersant, rheology modifying, and depressant properties could prove promising in combating the problems associated with these ore types. Quantitative evaluation by scanning electron microscopy (QEMSCAN) analysis revealed large quantities of serpentine and talc present within the ore sample used in this study, which led to a poor flotation response, as indicated by batch flotation tests. Using sodium metasilicate improved the recoveries and grades at high dosages (>1000 g/t). A suite of techniques was chosen to decouple sodium metasilicates' effects to answer why an improved flotation performance occurred. The zeta potential experiments indicate that improved recoveries are, in part, as a result of the reversal of serpentines surface charge, creating electrostatic repulsion between serpentine and valuable minerals which prevents the coating of valuable minerals by serpentine slimes. This corresponded with improved recoveries of a PGM proxy in the presence of serpentine slimes and a high sodium metasilicate dosage. Ore dilution and rheology tests indicate that decreased viscosity at high dosages also improved recoveries. This was supported by slower particle settling rates at high sodium metasilicate dosages during particle settling measurements. Talc micro-flotation tests revealed that the depression of talc occurred at higher sodium metasilicate dosages, which improved concentrate grade. This was supported by a QEMSCAN concentrate analysis of the sodium metasilicate batch flotation concentrates, which confirmed that talc, and other associated silicate minerals, were depressed at high sodium metasilicate dosages. The processing of near-surface altered ores is becoming an increasing problem worldwide and the use of sodium metasilicate proved valuable in mitigating the problems associated with the altered ore investigated in this study. DA - 2021 DB - OpenUCT DP - University of Cape Town KW - Alteration KW - phyllosilicate slimes KW - platinum group minerals LK - https://open.uct.ac.za PY - 2021 T1 - Investigating the use of sodium metasilicate to improve the flotation performance of altered PGE ores TI - Investigating the use of sodium metasilicate to improve the flotation performance of altered PGE ores UR - http://hdl.handle.net/11427/35888 ER - | en_ZA |
| dc.identifier.uri | http://hdl.handle.net/11427/35888 | |
| dc.identifier.vancouvercitation | Molifie A. Investigating the use of sodium metasilicate to improve the flotation performance of altered PGE ores. []. ,Faculty of Engineering and the Built Environment ,Department of Chemical Engineering, 2021 [cited yyyy month dd]. Available from: http://hdl.handle.net/11427/35888 | en_ZA |
| dc.language.rfc3066 | eng | |
| dc.publisher.department | Department of Chemical Engineering | |
| dc.publisher.faculty | Faculty of Engineering and the Built Environment | |
| dc.subject | Alteration | |
| dc.subject | phyllosilicate slimes | |
| dc.subject | platinum group minerals | |
| dc.title | Investigating the use of sodium metasilicate to improve the flotation performance of altered PGE ores | |
| dc.type | Doctoral Thesis | |
| dc.type.qualificationlevel | Doctoral | |
| dc.type.qualificationlevel | PhD |