The synthesis and host-guest activity of novel cyanoborate salts
Doctoral Thesis
1994
Permanent link to this Item
Authors
Supervisors
Journal Title
Link to Journal
Journal ISSN
Volume Title
Publisher
Publisher
University of Cape Town
Department
Faculty
License
Series
Abstract
Molecular recognition is a dynamic process based on distinct chemical interactions and not on passive fitting of a lock and key. Complex formation between host and guest molecules is often accompanied by conformational reorganisation, which makes it possible to engineer and fine-tune synthetic receptor analogues for optimal function and selectivity. This thesis primarily describes a supramolecular study of a novel family of airstable cyanoborate host compounds. The discovery of this clathrand family came about as a result of a study relating to the synthesis of an electrolyte for the Zebra car battery and the thesis begins with this aspect (Chapter 1). Although cyanoborates are well documented as synthetic intermediates in 1,2 migration reactions they have not been studied independently to any degree and this thesis constitutes the first significant study of this class of compound.
Description
Keywords
Reference:
Haueisen, R. 1994. The synthesis and host-guest activity of novel cyanoborate salts. University of Cape Town.