Synthetic, structural and molecular modelling studies of organoiron complexes of catalytic importance

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dc.contributor.advisorMoss, John Ren_ZA
dc.contributor.advisorMarias, Charlesen_ZA
dc.contributor.advisorNaidoo, Kevin Jen_ZA
dc.contributor.authorHill, Robert Oliveren_ZA
dc.date.accessioned2014-11-21T16:15:23Z
dc.date.available2014-11-21T16:15:23Z
dc.date.issued1999en_ZA
dc.descriptionIncludes bibliography.en_ZA
dc.description.abstractThe synthesis and characterization of a series of new alkyl dicarbonyl pentaznethylcyclopentadienyl iron compounds, [(η⁵-C₅(CH₃)₅)Fe(CO)₂R], is the starting point for an investigation of these compounds and their relevance as models for catalytic reactions. The compounds have been synthesized by the reaction of Na[(η⁵-C₅(CH₃)₅)Fe(CO)₂] with the appropriate n-alkyl chloride or bromide (R=n-C₃H₇ to n-C₁₂H₂₅). The majority of the compounds are new and have been fully characterized by microanalysis, IR, ¹H, and ¹³C NMR and mass spectrometry. The data are discussed and some properties and reactions of the compounds are described.en_ZA
dc.identifier.apacitationHill, R. O. (1999). <i>Synthetic, structural and molecular modelling studies of organoiron complexes of catalytic importance</i>. (Thesis). University of Cape Town ,Faculty of Science ,Department of Chemistry. Retrieved from http://hdl.handle.net/11427/9772en_ZA
dc.identifier.chicagocitationHill, Robert Oliver. <i>"Synthetic, structural and molecular modelling studies of organoiron complexes of catalytic importance."</i> Thesis., University of Cape Town ,Faculty of Science ,Department of Chemistry, 1999. http://hdl.handle.net/11427/9772en_ZA
dc.identifier.citationHill, R. 1999. Synthetic, structural and molecular modelling studies of organoiron complexes of catalytic importance. University of Cape Town.en_ZA
dc.identifier.ris TY - Thesis / Dissertation AU - Hill, Robert Oliver AB - The synthesis and characterization of a series of new alkyl dicarbonyl pentaznethylcyclopentadienyl iron compounds, [(η⁵-C₅(CH₃)₅)Fe(CO)₂R], is the starting point for an investigation of these compounds and their relevance as models for catalytic reactions. The compounds have been synthesized by the reaction of Na[(η⁵-C₅(CH₃)₅)Fe(CO)₂] with the appropriate n-alkyl chloride or bromide (R=n-C₃H₇ to n-C₁₂H₂₅). The majority of the compounds are new and have been fully characterized by microanalysis, IR, ¹H, and ¹³C NMR and mass spectrometry. The data are discussed and some properties and reactions of the compounds are described. DA - 1999 DB - OpenUCT DP - University of Cape Town LK - https://open.uct.ac.za PB - University of Cape Town PY - 1999 T1 - Synthetic, structural and molecular modelling studies of organoiron complexes of catalytic importance TI - Synthetic, structural and molecular modelling studies of organoiron complexes of catalytic importance UR - http://hdl.handle.net/11427/9772 ER - en_ZA
dc.identifier.urihttp://hdl.handle.net/11427/9772
dc.identifier.vancouvercitationHill RO. Synthetic, structural and molecular modelling studies of organoiron complexes of catalytic importance. [Thesis]. University of Cape Town ,Faculty of Science ,Department of Chemistry, 1999 [cited yyyy month dd]. Available from: http://hdl.handle.net/11427/9772en_ZA
dc.language.isoengen_ZA
dc.publisher.departmentDepartment of Chemistryen_ZA
dc.publisher.facultyFaculty of Scienceen_ZA
dc.publisher.institutionUniversity of Cape Town
dc.subject.otherChemistryen_ZA
dc.titleSynthetic, structural and molecular modelling studies of organoiron complexes of catalytic importanceen_ZA
dc.typeDoctoral Thesis
dc.type.qualificationlevelDoctoral
dc.type.qualificationnamePhDen_ZA
uct.type.filetypeText
uct.type.filetypeImage
uct.type.publicationResearchen_ZA
uct.type.resourceThesisen_ZA
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