Chloromethyl and methoxymethyl transition metal complexes : an investigation into their synthesis and reactivity

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dc.contributor.advisorMoss, John Ren_ZA
dc.contributor.authorPelling, Simonen_ZA
dc.date.accessioned2016-08-22T12:26:03Z
dc.date.available2016-08-22T12:26:03Z
dc.date.issued1981en_ZA
dc.descriptionBibliography: p. 125-129.en_ZA
dc.description.abstractTransition metal methoxymethyl and chloromethyl complexes may be versatile starting materials for the synthesis of several types of new complexes, including hydroxymethyl and carbene complexes, respectively [LₙMCH₂OH] and [LₙMCH₂]⁺ (M=transition metal, L=ligands). Hydroxymethyl and carbene transition metal complexes are models of catalytic intermediates in the Fischer-Tropsch reaction. We have synthesized the new chloromethyl complexes [Ru(Cp)(CO)₂CH₂CI], [Re(CO)₅CH₂CI], and cis-[Mn(CO)₄(PPh₃)CH₂CI], and the new methoxymethyl The existence of rotational isomerism in the complexes [Ru(Cp)(CO)₂CH₂ocH₃] and the previously reported [Fe(Cp)(CO)₂CH₂OCH₃],⁴⁸ is proposed on the basis of infrared data. Mass spectra of several methoxymethyl and chloromethyl transition metal complexes have been recorded.en_ZA
dc.identifier.apacitationPelling, S. (1981). <i>Chloromethyl and methoxymethyl transition metal complexes : an investigation into their synthesis and reactivity</i>. (Thesis). University of Cape Town ,Faculty of Science ,Department of Chemistry. Retrieved from http://hdl.handle.net/11427/21426en_ZA
dc.identifier.chicagocitationPelling, Simon. <i>"Chloromethyl and methoxymethyl transition metal complexes : an investigation into their synthesis and reactivity."</i> Thesis., University of Cape Town ,Faculty of Science ,Department of Chemistry, 1981. http://hdl.handle.net/11427/21426en_ZA
dc.identifier.citationPelling, S. 1981. Chloromethyl and methoxymethyl transition metal complexes : an investigation into their synthesis and reactivity. University of Cape Town.en_ZA
dc.identifier.ris TY - Thesis / Dissertation AU - Pelling, Simon AB - Transition metal methoxymethyl and chloromethyl complexes may be versatile starting materials for the synthesis of several types of new complexes, including hydroxymethyl and carbene complexes, respectively [LₙMCH₂OH] and [LₙMCH₂]⁺ (M=transition metal, L=ligands). Hydroxymethyl and carbene transition metal complexes are models of catalytic intermediates in the Fischer-Tropsch reaction. We have synthesized the new chloromethyl complexes [Ru(Cp)(CO)₂CH₂CI], [Re(CO)₅CH₂CI], and cis-[Mn(CO)₄(PPh₃)CH₂CI], and the new methoxymethyl The existence of rotational isomerism in the complexes [Ru(Cp)(CO)₂CH₂ocH₃] and the previously reported [Fe(Cp)(CO)₂CH₂OCH₃],⁴⁸ is proposed on the basis of infrared data. Mass spectra of several methoxymethyl and chloromethyl transition metal complexes have been recorded. DA - 1981 DB - OpenUCT DP - University of Cape Town LK - https://open.uct.ac.za PB - University of Cape Town PY - 1981 T1 - Chloromethyl and methoxymethyl transition metal complexes : an investigation into their synthesis and reactivity TI - Chloromethyl and methoxymethyl transition metal complexes : an investigation into their synthesis and reactivity UR - http://hdl.handle.net/11427/21426 ER - en_ZA
dc.identifier.urihttp://hdl.handle.net/11427/21426
dc.identifier.vancouvercitationPelling S. Chloromethyl and methoxymethyl transition metal complexes : an investigation into their synthesis and reactivity. [Thesis]. University of Cape Town ,Faculty of Science ,Department of Chemistry, 1981 [cited yyyy month dd]. Available from: http://hdl.handle.net/11427/21426en_ZA
dc.language.isoengen_ZA
dc.publisher.departmentDepartment of Chemistryen_ZA
dc.publisher.facultyFaculty of Scienceen_ZA
dc.publisher.institutionUniversity of Cape Town
dc.titleChloromethyl and methoxymethyl transition metal complexes : an investigation into their synthesis and reactivityen_ZA
dc.typeMaster Thesis
dc.type.qualificationlevelMasters
dc.type.qualificationnameMScen_ZA
uct.type.filetypeText
uct.type.filetypeImage
uct.type.publicationResearchen_ZA
uct.type.resourceThesisen_ZA
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