Structures and thermal analyses of Werner clathrates and coordination polymers

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dc.contributor.advisorNassimbeni, Luigi Ren_ZA
dc.contributor.advisorCaira, Mino Ren_ZA
dc.contributor.advisorBourne, Susan Aen_ZA
dc.contributor.authorKilkenny, Mairien_ZA
dc.date.accessioned2016-03-17T07:18:51Z
dc.date.available2016-03-17T07:18:51Z
dc.date.issued2001en_ZA
dc.descriptionIncludes bibliographical references.en_ZA
dc.description.abstractThe crystal structures of several organometallic host complexes and their inclusion compounds with small, polar, organic guests have been elucidated. These compounds form a diverse range of structure types, from hydrogen bonded networks of Werner-type inclusion compounds to one- and two- dimensional coordination polymers. Depending on the packing arrangement of the host molecules in the clathrate, the guest molecules (G) may become trapped in cages, stacked in one-dimensional channels or sandwiched between layers of host molecules. Examples of all three clathrate types can be found in the different inclusion compounds presented here. The crystal structures of several organometallic host complexes and their inclusion compounds with small, polar, organic guests have been elucidated. These compounds form a diverse range of structure types, from hydrogen bonded networks of Werner-type inclusion compounds to one- and two- dimensional coordination polymers. Depending on the packing arrangement of the host molecules in the clathrate, the guest molecules (G) may become trapped in cages, stacked in one-dimensional channels or sandwiched between layers of host molecules. Examples of all three clathrate types can be found in the different inclusion compounds presented here. The crystal structures of twelve Werner clathrates and four coordination polymers were solved using single crystal x-ray diffraction techniques. In addition, all compounds were characterised by thermal analysis techniques, including differential scanning calorimetry, thermogravimetry and hot-stage microscopy.en_ZA
dc.identifier.apacitationKilkenny, M. (2001). <i>Structures and thermal analyses of Werner clathrates and coordination polymers</i>. (Thesis). University of Cape Town ,Faculty of Science ,Department of Chemistry. Retrieved from http://hdl.handle.net/11427/17903en_ZA
dc.identifier.chicagocitationKilkenny, Mairi. <i>"Structures and thermal analyses of Werner clathrates and coordination polymers."</i> Thesis., University of Cape Town ,Faculty of Science ,Department of Chemistry, 2001. http://hdl.handle.net/11427/17903en_ZA
dc.identifier.citationKilkenny, M. 2001. Structures and thermal analyses of Werner clathrates and coordination polymers. University of Cape Town.en_ZA
dc.identifier.ris TY - Thesis / Dissertation AU - Kilkenny, Mairi AB - The crystal structures of several organometallic host complexes and their inclusion compounds with small, polar, organic guests have been elucidated. These compounds form a diverse range of structure types, from hydrogen bonded networks of Werner-type inclusion compounds to one- and two- dimensional coordination polymers. Depending on the packing arrangement of the host molecules in the clathrate, the guest molecules (G) may become trapped in cages, stacked in one-dimensional channels or sandwiched between layers of host molecules. Examples of all three clathrate types can be found in the different inclusion compounds presented here. The crystal structures of several organometallic host complexes and their inclusion compounds with small, polar, organic guests have been elucidated. These compounds form a diverse range of structure types, from hydrogen bonded networks of Werner-type inclusion compounds to one- and two- dimensional coordination polymers. Depending on the packing arrangement of the host molecules in the clathrate, the guest molecules (G) may become trapped in cages, stacked in one-dimensional channels or sandwiched between layers of host molecules. Examples of all three clathrate types can be found in the different inclusion compounds presented here. The crystal structures of twelve Werner clathrates and four coordination polymers were solved using single crystal x-ray diffraction techniques. In addition, all compounds were characterised by thermal analysis techniques, including differential scanning calorimetry, thermogravimetry and hot-stage microscopy. DA - 2001 DB - OpenUCT DP - University of Cape Town LK - https://open.uct.ac.za PB - University of Cape Town PY - 2001 T1 - Structures and thermal analyses of Werner clathrates and coordination polymers TI - Structures and thermal analyses of Werner clathrates and coordination polymers UR - http://hdl.handle.net/11427/17903 ER - en_ZA
dc.identifier.urihttp://hdl.handle.net/11427/17903
dc.identifier.vancouvercitationKilkenny M. Structures and thermal analyses of Werner clathrates and coordination polymers. [Thesis]. University of Cape Town ,Faculty of Science ,Department of Chemistry, 2001 [cited yyyy month dd]. Available from: http://hdl.handle.net/11427/17903en_ZA
dc.language.isoengen_ZA
dc.publisher.departmentDepartment of Chemistryen_ZA
dc.publisher.facultyFaculty of Scienceen_ZA
dc.publisher.institutionUniversity of Cape Town
dc.subject.otherChemistryen_ZA
dc.titleStructures and thermal analyses of Werner clathrates and coordination polymersen_ZA
dc.typeMaster Thesis
dc.type.qualificationlevelMasters
dc.type.qualificationnameMScen_ZA
uct.type.filetypeText
uct.type.filetypeImage
uct.type.publicationResearchen_ZA
uct.type.resourceThesisen_ZA
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