Synthetic studies towards an organometallic rotaxane

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dc.contributor.advisorMoss
dc.contributor.authorMare, Jacques Simon Fife
dc.date.accessioned2023-09-15T14:23:52Z
dc.date.available2023-09-15T14:23:52Z
dc.date.issued1996
dc.date.updated2023-09-15T14:23:32Z
dc.description.abstractThe synthesis of interlocking molecules such as rotaxanes and catenanes is a branch of supramolecular chemistry of particular current interest. The aim of this work was to assess the viability of the synthesis of an organometallic rotaxane in which the transition metal is covalently bonded to a carbon atom of an alkyl group. The formation of a rotaxane using the host cyclophane, cyclobis (paraquat-pphenylene), formed by a template effect, has been investigated using our chiral organometallic polyether.
dc.identifier.apacitationMare, J. S. F. (1996). <i>Synthetic studies towards an organometallic rotaxane</i>. (). ,Faculty of Science ,Department of Chemistry. Retrieved from http://hdl.handle.net/11427/38703en_ZA
dc.identifier.chicagocitationMare, Jacques Simon Fife. <i>"Synthetic studies towards an organometallic rotaxane."</i> ., ,Faculty of Science ,Department of Chemistry, 1996. http://hdl.handle.net/11427/38703en_ZA
dc.identifier.citationMare, J.S.F. 1996. Synthetic studies towards an organometallic rotaxane. . ,Faculty of Science ,Department of Chemistry. http://hdl.handle.net/11427/38703en_ZA
dc.identifier.ris TY - Master Thesis AU - Mare, Jacques Simon Fife AB - The synthesis of interlocking molecules such as rotaxanes and catenanes is a branch of supramolecular chemistry of particular current interest. The aim of this work was to assess the viability of the synthesis of an organometallic rotaxane in which the transition metal is covalently bonded to a carbon atom of an alkyl group. The formation of a rotaxane using the host cyclophane, cyclobis (paraquat-pphenylene), formed by a template effect, has been investigated using our chiral organometallic polyether. DA - 1996 DB - OpenUCT DP - University of Cape Town KW - Chemistry LK - https://open.uct.ac.za PY - 1996 T1 - Synthetic studies towards an organometallic rotaxane TI - Synthetic studies towards an organometallic rotaxane UR - http://hdl.handle.net/11427/38703 ER - en_ZA
dc.identifier.urihttp://hdl.handle.net/11427/38703
dc.identifier.vancouvercitationMare JSF. Synthetic studies towards an organometallic rotaxane. []. ,Faculty of Science ,Department of Chemistry, 1996 [cited yyyy month dd]. Available from: http://hdl.handle.net/11427/38703en_ZA
dc.language.rfc3066eng
dc.publisher.departmentDepartment of Chemistry
dc.publisher.facultyFaculty of Science
dc.subjectChemistry
dc.titleSynthetic studies towards an organometallic rotaxane
dc.typeMaster Thesis
dc.type.qualificationlevelMasters
dc.type.qualificationlevelMSc
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