Selective criteria in Werner clathrates

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dc.contributor.authorLavelle, Laurence
dc.date.accessioned2017-01-27T08:36:32Z
dc.date.available2017-01-27T08:36:32Z
dc.date.issued1988
dc.date.updated2016-12-06T11:23:45Z
dc.description.abstractWe have elucidated the structures of a series of Werner Clathrates with systematically changing guest molecules. The host is the inorganic coordination compound bis(isothiocyanato)tetra(4-vinylpyridine)nickel(II), [Ni(NCS)2(4-ViPy)4]. The guests are mixtures of tetrahydrofuran and the cyclic hydrocarbons: cyclohexane, cyclohexene, 1,3-cYclohexadiene, 1,4-cyclohexadiene and benzene. Host to guest ratios were elucidated by density and proton nuclear magnetic resonance spectroscopy. The thermal characteristics of the compounds were analysed by thermogravimetric analysis and differen.tial thermal analysis. The structures of two related compounds [Ni(NCS)2(Py)4] and [Ni(NCS)2(Py)4].nbenzene were also studied.
dc.identifier.apacitationLavelle, L. (1988). <i>Selective criteria in Werner clathrates</i>. (). University of Cape Town ,Faculty of Science ,Department of Chemistry. Retrieved from http://hdl.handle.net/11427/23608en_ZA
dc.identifier.chicagocitationLavelle, Laurence. <i>"Selective criteria in Werner clathrates."</i> ., University of Cape Town ,Faculty of Science ,Department of Chemistry, 1988. http://hdl.handle.net/11427/23608en_ZA
dc.identifier.citationLavelle, L. 1988. Selective criteria in Werner clathrates. University of Cape Town.en_ZA
dc.identifier.ris TY - Thesis / Dissertation AU - Lavelle, Laurence AB - We have elucidated the structures of a series of Werner Clathrates with systematically changing guest molecules. The host is the inorganic coordination compound bis(isothiocyanato)tetra(4-vinylpyridine)nickel(II), [Ni(NCS)2(4-ViPy)4]. The guests are mixtures of tetrahydrofuran and the cyclic hydrocarbons: cyclohexane, cyclohexene, 1,3-cYclohexadiene, 1,4-cyclohexadiene and benzene. Host to guest ratios were elucidated by density and proton nuclear magnetic resonance spectroscopy. The thermal characteristics of the compounds were analysed by thermogravimetric analysis and differen.tial thermal analysis. The structures of two related compounds [Ni(NCS)2(Py)4] and [Ni(NCS)2(Py)4].nbenzene were also studied. DA - 1988 DB - OpenUCT DP - University of Cape Town LK - https://open.uct.ac.za PB - University of Cape Town PY - 1988 T1 - Selective criteria in Werner clathrates TI - Selective criteria in Werner clathrates UR - http://hdl.handle.net/11427/23608 ER - en_ZA
dc.identifier.urihttp://hdl.handle.net/11427/23608
dc.identifier.vancouvercitationLavelle L. Selective criteria in Werner clathrates. []. University of Cape Town ,Faculty of Science ,Department of Chemistry, 1988 [cited yyyy month dd]. Available from: http://hdl.handle.net/11427/23608en_ZA
dc.language.isoeng
dc.publisher.departmentDepartment of Chemistryen_ZA
dc.publisher.facultyFaculty of Scienceen_ZA
dc.publisher.institutionUniversity of Cape Town
dc.subject.otherClathrate compounds
dc.titleSelective criteria in Werner clathrates
dc.typeThesis
dc.type.qualificationlevelMasters
dc.type.qualificationnameMSc
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