Desorption kinetics of a xanthenol-dioxane clathrate
| dc.contributor.author | Jacobs, Ayesha | |
| dc.contributor.author | Nassimbeni, Luigi R | |
| dc.contributor.author | Taljaard, Benjamin | |
| dc.date.accessioned | 2016-01-22T10:11:08Z | |
| dc.date.available | 2016-01-22T10:11:08Z | |
| dc.date.issued | 2004 | |
| dc.date.updated | 2016-01-19T09:50:02Z | |
| dc.description.abstract | The host xanthenol compound forms a 1:1 clathrate with dioxane, namely 9-(1-naphthyl)-9H-xanthen-9-ol–1,4-dioxane, C23H16O2·C4H8O2. The structure of this clathrate is reported, along with a study of the kinetics of desolvation and the determination of an activation energy. The guest molecules are stabilized by Ohost—H⋯Oguest hydrogen bonds [O—H = 0.968 (2) Å, O⋯O = 2.7532 (13) Å and O—H⋯O = 151.9 (4)°]. | en_ZA |
| dc.identifier | http://dx.doi.org/10.1107/S0108270104017792 | |
| dc.identifier.apacitation | Jacobs, A., Nassimbeni, L. R., & Taljaard, B. (2004). Desorption kinetics of a xanthenol-dioxane clathrate. <i>Acta Crystallographica</i>, http://hdl.handle.net/11427/16512 | en_ZA |
| dc.identifier.chicagocitation | Jacobs, Ayesha, Luigi R Nassimbeni, and Benjamin Taljaard "Desorption kinetics of a xanthenol-dioxane clathrate." <i>Acta Crystallographica</i> (2004) http://hdl.handle.net/11427/16512 | en_ZA |
| dc.identifier.citation | Jacobs, A., Nassimbeni, L. R., & Taljaard, B. (2004). Desorption kinetics of a xanthenol–dioxane clathrate. Acta Crystallographica Section C: Crystal Structure Communications, 60(9), 668-670. | en_ZA |
| dc.identifier.issn | 0365-110X | en_ZA |
| dc.identifier.ris | TY - Journal Article AU - Jacobs, Ayesha AU - Nassimbeni, Luigi R AU - Taljaard, Benjamin AB - The host xanthenol compound forms a 1:1 clathrate with dioxane, namely 9-(1-naphthyl)-9H-xanthen-9-ol–1,4-dioxane, C23H16O2·C4H8O2. The structure of this clathrate is reported, along with a study of the kinetics of desolvation and the determination of an activation energy. The guest molecules are stabilized by Ohost—H⋯Oguest hydrogen bonds [O—H = 0.968 (2) Å, O⋯O = 2.7532 (13) Å and O—H⋯O = 151.9 (4)°]. DA - 2004 DB - OpenUCT DP - University of Cape Town J1 - Acta Crystallographica LK - https://open.uct.ac.za PB - University of Cape Town PY - 2004 SM - 0365-110X T1 - Desorption kinetics of a xanthenol-dioxane clathrate TI - Desorption kinetics of a xanthenol-dioxane clathrate UR - http://hdl.handle.net/11427/16512 ER - | en_ZA |
| dc.identifier.uri | http://hdl.handle.net/11427/16512 | |
| dc.identifier.vancouvercitation | Jacobs A, Nassimbeni LR, Taljaard B. Desorption kinetics of a xanthenol-dioxane clathrate. Acta Crystallographica. 2004; http://hdl.handle.net/11427/16512. | en_ZA |
| dc.language | eng | en_ZA |
| dc.publisher | International Union of Crystallography | en_ZA |
| dc.publisher.department | Department of Chemistry | en_ZA |
| dc.publisher.faculty | Faculty of Science | en_ZA |
| dc.publisher.institution | University of Cape Town | |
| dc.source | Acta Crystallographica | en_ZA |
| dc.source.uri | http://journals.iucr.org/c/ | |
| dc.title | Desorption kinetics of a xanthenol-dioxane clathrate | en_ZA |
| dc.type | Journal Article | en_ZA |
| uct.subject.keywords | xanthenol-dioxane clathrate | en_ZA |
| uct.type.filetype | Text | |
| uct.type.filetype | Image | |
| uct.type.publication | Research | en_ZA |
| uct.type.resource | Article | en_ZA |