Characterization of Au catalysts

dc.contributor.authorVan Heerden, T
dc.contributor.authorHill, M
dc.contributor.authorCase, J
dc.contributor.authorVan Steen, E
dc.date.accessioned2017-06-26T09:43:01Z
dc.date.available2017-06-26T09:43:01Z
dc.date.issued2012
dc.date.updated2016-01-11T09:40:15Z
dc.description.abstractA range of supported gold catalysts was prepared by ion exchange, varying many of the preparation variables, including concentration in the precursor solution, washing procedure, as well as drying and calcination procedures. These catalysts have been characterized extensively. TEM images show essentially the same crystallite size distributions, between 2–5 nm, for almost all catalysts, the only exception being catalysts not washed in ammonia, which did not show any small crystallites. Additional characterization with SEM yielded an interesting discovery. Catalysts that appear identical on the TEM also contain some large crystallites in the range of 50–500 nm. Differences in dispersion due to the drying procedure not seen on the TEM can now be observed. Oxygen chemisorption is being investigated as an additional method to characterize gold based catalysts to complementthe typically used electron microscope techniques.
dc.identifier.apacitationVan Heerden, T., Hill, M., Case, J., & Van Steen, E. (2012). Characterization of Au catalysts. <i>Journal of the South African Institute of Mining and Metallurgy</i>, http://hdl.handle.net/11427/24634en_ZA
dc.identifier.chicagocitationVan Heerden, T, M Hill, J Case, and E Van Steen "Characterization of Au catalysts." <i>Journal of the South African Institute of Mining and Metallurgy</i> (2012) http://hdl.handle.net/11427/24634en_ZA
dc.identifier.citationVan Heerden, T;Hill, M;Case, J M;Van Steen, EWJ. (2012). Characterization of Au catalysts, 7A:527-533
dc.identifier.ris TY - Journal Article AU - Van Heerden, T AU - Hill, M AU - Case, J AU - Van Steen, E AB - A range of supported gold catalysts was prepared by ion exchange, varying many of the preparation variables, including concentration in the precursor solution, washing procedure, as well as drying and calcination procedures. These catalysts have been characterized extensively. TEM images show essentially the same crystallite size distributions, between 2–5 nm, for almost all catalysts, the only exception being catalysts not washed in ammonia, which did not show any small crystallites. Additional characterization with SEM yielded an interesting discovery. Catalysts that appear identical on the TEM also contain some large crystallites in the range of 50–500 nm. Differences in dispersion due to the drying procedure not seen on the TEM can now be observed. Oxygen chemisorption is being investigated as an additional method to characterize gold based catalysts to complementthe typically used electron microscope techniques. DA - 2012 DB - OpenUCT DP - University of Cape Town J1 - Journal of the South African Institute of Mining and Metallurgy LK - https://open.uct.ac.za PB - University of Cape Town PY - 2012 T1 - Characterization of Au catalysts TI - Characterization of Au catalysts UR - http://hdl.handle.net/11427/24634 ER - en_ZA
dc.identifier.urihttp://hdl.handle.net/11427/24634
dc.identifier.vancouvercitationVan Heerden T, Hill M, Case J, Van Steen E. Characterization of Au catalysts. Journal of the South African Institute of Mining and Metallurgy. 2012; http://hdl.handle.net/11427/24634.en_ZA
dc.language.isoeng
dc.publisher.departmentCentre for Catalysis Researchen_ZA
dc.publisher.facultyFaculty of Engineering and the Built Environment
dc.publisher.institutionUniversity of Cape Town
dc.sourceJournal of the South African Institute of Mining and Metallurgy
dc.source.urihttp://www.saimm.co.za/publications/journal-papers
dc.titleCharacterization of Au catalysts
dc.typeJournal Articleen_ZA
uct.type.filetype
uct.type.filetypeText
uct.type.filetypeImage
uct.type.publicationResearchen_ZA
uct.type.resourceArticleen_ZA
Files
Original bundle
Now showing 1 - 1 of 1
Loading...
Thumbnail Image
Name:
van Heerden_Article_2012.pdf
Size:
555.71 KB
Format:
Adobe Portable Document Format
Description:
License bundle
Now showing 1 - 1 of 1
Loading...
Thumbnail Image
Name:
license.txt
Size:
1.72 KB
Format:
Item-specific license agreed upon to submission
Description:
Collections