A low - δ 18 O intrusive breccia from the Koegel Fontein complex, South Africa

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dc.contributor.advisorHarris, Chrisen_ZA
dc.contributor.authorOlianti, Camille Andrea Elisaen_ZA
dc.date.accessioned2016-07-08T11:45:03Z
dc.date.available2016-07-08T11:45:03Z
dc.date.issued2016en_ZA
dc.descriptionIncludes bibliographical referencesen_ZA
dc.description.abstractThe ~135 Ma Koegel Fontein complex, 350 km north of Cape Town, has rocks with abnormally low δ 18 O values, as low as - 5.2 ‰. The rocks with the lowest δ 18 O values belong to an intrusive breccia and have a fine - grained, black matrix. The silica content of these breccia rocks ranges between 44 - 68 wt %, their whole - rock δ 18 O values vary between - 5.2 ‰ and +1.8 ‰ , and their water content is between 0.2 - 1.1 wt %. The major and trace element composition of the breccia rocks is consistent with them containing variable proportions of bentonite, alkali basalt, gneiss, and epidote - and xenolith - rich material. Mapping indicates that the initial intrusion was an alkali basalt dyke and a bostonite dyke that were then intruded by two breccia plugs that extended along the planes of weakness created by the pre - existing dykes, forming two sub - parallel breccia dykes. The water content of the breccia rocks is low (average <1.0 wt %) and is consistent with interaction with fluids at a relatively high temperature (> 300°C). These fluids interacted with the rocks from both dykes and are responsible for their 18 O - depletion. On the basis of the O - and H - isotope composition of the breccia rocks, the δ 18 O value calculated for the fluids in equilibrium with the breccia rock s is approximately - 10.8 ± 0.2 ‰. This low δ 18 O value of the meteoric fluids is too low for the low latitude and warm climate at ~135 Ma and indicates that 18 O - depletion at Koegel Fontein predates the intrusion of the complex in the Cretaceous. It is possible that low - δ 18 O fluids circulated through the country rock during the Pan African when crustal reworking enabled deep circulation of surface water. This period of crustal reworking coincides with a 'Snowball Earth' event and would have been accompanied by 18 O - depleted meteoric water. In the Cretaceous, it is assumed that a mantle plume heated the crust, causing dehydration before partial melting of the crust. The initial low - δ 18 O fluids are effectively metamorphic fluids in equilibrium with the rock. It i s proposed that the initial loss of these fluids became explosive. These fluids migrated along the pre - existing alkali basalt and bentonite dykes, incorporating fragments of alkali basalt, bostonite, and country rock gneiss. This xenolith - rich fluidised material was then emplaced rapidly into the crusten_ZA
dc.identifier.apacitationOlianti, C. A. E. (2016). <i>A low - δ 18 O intrusive breccia from the Koegel Fontein complex, South Africa</i>. (Thesis). University of Cape Town ,Faculty of Science ,Department of Geological Sciences. Retrieved from http://hdl.handle.net/11427/20270en_ZA
dc.identifier.chicagocitationOlianti, Camille Andrea Elisa. <i>"A low - δ 18 O intrusive breccia from the Koegel Fontein complex, South Africa."</i> Thesis., University of Cape Town ,Faculty of Science ,Department of Geological Sciences, 2016. http://hdl.handle.net/11427/20270en_ZA
dc.identifier.citationOlianti, C. 2016. A low - δ 18 O intrusive breccia from the Koegel Fontein complex, South Africa. University of Cape Town.en_ZA
dc.identifier.ris TY - Thesis / Dissertation AU - Olianti, Camille Andrea Elisa AB - The ~135 Ma Koegel Fontein complex, 350 km north of Cape Town, has rocks with abnormally low δ 18 O values, as low as - 5.2 ‰. The rocks with the lowest δ 18 O values belong to an intrusive breccia and have a fine - grained, black matrix. The silica content of these breccia rocks ranges between 44 - 68 wt %, their whole - rock δ 18 O values vary between - 5.2 ‰ and +1.8 ‰ , and their water content is between 0.2 - 1.1 wt %. The major and trace element composition of the breccia rocks is consistent with them containing variable proportions of bentonite, alkali basalt, gneiss, and epidote - and xenolith - rich material. Mapping indicates that the initial intrusion was an alkali basalt dyke and a bostonite dyke that were then intruded by two breccia plugs that extended along the planes of weakness created by the pre - existing dykes, forming two sub - parallel breccia dykes. The water content of the breccia rocks is low (average <1.0 wt %) and is consistent with interaction with fluids at a relatively high temperature (> 300°C). These fluids interacted with the rocks from both dykes and are responsible for their 18 O - depletion. On the basis of the O - and H - isotope composition of the breccia rocks, the δ 18 O value calculated for the fluids in equilibrium with the breccia rock s is approximately - 10.8 ± 0.2 ‰. This low δ 18 O value of the meteoric fluids is too low for the low latitude and warm climate at ~135 Ma and indicates that 18 O - depletion at Koegel Fontein predates the intrusion of the complex in the Cretaceous. It is possible that low - δ 18 O fluids circulated through the country rock during the Pan African when crustal reworking enabled deep circulation of surface water. This period of crustal reworking coincides with a 'Snowball Earth' event and would have been accompanied by 18 O - depleted meteoric water. In the Cretaceous, it is assumed that a mantle plume heated the crust, causing dehydration before partial melting of the crust. The initial low - δ 18 O fluids are effectively metamorphic fluids in equilibrium with the rock. It i s proposed that the initial loss of these fluids became explosive. These fluids migrated along the pre - existing alkali basalt and bentonite dykes, incorporating fragments of alkali basalt, bostonite, and country rock gneiss. This xenolith - rich fluidised material was then emplaced rapidly into the crust DA - 2016 DB - OpenUCT DP - University of Cape Town LK - https://open.uct.ac.za PB - University of Cape Town PY - 2016 T1 - A low - δ 18 O intrusive breccia from the Koegel Fontein complex, South Africa TI - A low - δ 18 O intrusive breccia from the Koegel Fontein complex, South Africa UR - http://hdl.handle.net/11427/20270 ER - en_ZA
dc.identifier.urihttp://hdl.handle.net/11427/20270
dc.identifier.vancouvercitationOlianti CAE. A low - δ 18 O intrusive breccia from the Koegel Fontein complex, South Africa. [Thesis]. University of Cape Town ,Faculty of Science ,Department of Geological Sciences, 2016 [cited yyyy month dd]. Available from: http://hdl.handle.net/11427/20270en_ZA
dc.language.isoengen_ZA
dc.publisher.departmentDepartment of Geological Sciencesen_ZA
dc.publisher.facultyFaculty of Scienceen_ZA
dc.publisher.institutionUniversity of Cape Town
dc.subject.otherGeological Sciencesen_ZA
dc.titleA low - δ 18 O intrusive breccia from the Koegel Fontein complex, South Africaen_ZA
dc.typeMaster Thesis
dc.type.qualificationlevelMasters
dc.type.qualificationnameMScen_ZA
uct.type.filetypeText
uct.type.filetypeImage
uct.type.publicationResearchen_ZA
uct.type.resourceThesisen_ZA
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