Aromatization of 1-hexene and 1-octene by gallium/H-ZSM-5 catalysts.

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dc.contributor.authorNash, R
dc.contributor.authorDry, M
dc.contributor.authorO'Connor, C
dc.date.accessioned2016-07-29T10:46:50Z
dc.date.available2016-07-29T10:46:50Z
dc.date.issued1996
dc.date.updated2016-07-28T13:18:25Z
dc.description.abstractGallium/H-ZSM-5 zeolite catalysts were tested for the aromatization of long-chain alkenes, namely 1-hexene and 1-octene. Aromatic yields of ca. 70% were obtained, which are similar to those reported in the literature for propene aromatization. The catalysts tested were prepared by impregnation by incipient wetness of gallium nitrate, ion-exchange with gallium nitrate and by physical mixing with β-gallium oxide crystallites. Hydrogen pretreatment improved the selectivity to aromatic products of gallium/H-ZSM-5 catalysts prepared by physical mixing with β-gallium oxide, but decreased aromatic selectivity for catalysts prepared by ion-exchange and impregnation.en_ZA
dc.identifierhttp://dx.doi.org/10.1016/0926-860X(95)00198-0
dc.identifier.apacitationNash, R., Dry, M., & O'Connor, C. (1996). Aromatization of 1-hexene and 1-octene by gallium/H-ZSM-5 catalysts. <i>Applied Catalysis A: General</i>, http://hdl.handle.net/11427/21026en_ZA
dc.identifier.chicagocitationNash, R, M Dry, and C O'Connor "Aromatization of 1-hexene and 1-octene by gallium/H-ZSM-5 catalysts." <i>Applied Catalysis A: General</i> (1996) http://hdl.handle.net/11427/21026en_ZA
dc.identifier.citationNash, R. J., Dry, M. E., & O'Connor, C. T. (1996). Aromatization of 1-hexene and 1-octene by gallium/H-ZSM-5 catalysts. Applied Catalysis A: General, 134(2), 285-297.en_ZA
dc.identifier.issn0926-860Xen_ZA
dc.identifier.ris TY - Journal Article AU - Nash, R AU - Dry, M AU - O'Connor, C AB - Gallium/H-ZSM-5 zeolite catalysts were tested for the aromatization of long-chain alkenes, namely 1-hexene and 1-octene. Aromatic yields of ca. 70% were obtained, which are similar to those reported in the literature for propene aromatization. The catalysts tested were prepared by impregnation by incipient wetness of gallium nitrate, ion-exchange with gallium nitrate and by physical mixing with β-gallium oxide crystallites. Hydrogen pretreatment improved the selectivity to aromatic products of gallium/H-ZSM-5 catalysts prepared by physical mixing with β-gallium oxide, but decreased aromatic selectivity for catalysts prepared by ion-exchange and impregnation. DA - 1996 DB - OpenUCT DP - University of Cape Town J1 - Applied Catalysis A: General LK - https://open.uct.ac.za PB - University of Cape Town PY - 1996 SM - 0926-860X T1 - Aromatization of 1-hexene and 1-octene by gallium/H-ZSM-5 catalysts TI - Aromatization of 1-hexene and 1-octene by gallium/H-ZSM-5 catalysts UR - http://hdl.handle.net/11427/21026 ER - en_ZA
dc.identifier.urihttp://hdl.handle.net/11427/21026
dc.identifier.vancouvercitationNash R, Dry M, O'Connor C. Aromatization of 1-hexene and 1-octene by gallium/H-ZSM-5 catalysts. Applied Catalysis A: General. 1996; http://hdl.handle.net/11427/21026.en_ZA
dc.languageengen_ZA
dc.publisherElsevieren_ZA
dc.publisher.institutionUniversity of Cape Town
dc.rightsCreative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/en_ZA
dc.sourceApplied Catalysis A: Generalen_ZA
dc.source.urihttp://www.journals.elsevier.com/applied-catalysis-a-general/
dc.subject.otherAromatization
dc.subject.otherAlkenes
dc.subject.otherGallium
dc.subject.otherH-ZSM-5 zeolite
dc.subject.otherHydrogen treatments
dc.titleAromatization of 1-hexene and 1-octene by gallium/H-ZSM-5 catalysts.en_ZA
dc.typeJournal Articleen_ZA
uct.type.filetypeText
uct.type.filetypeImage
uct.type.publicationResearchen_ZA
uct.type.resourceArticleen_ZA
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