Synthesis and evaluation of bioluminescent probes as tools for anticancer drug discovery

dc.contributor.advisorJardine, Mogamat
dc.contributor.authorFredericks, Maryam
dc.date.accessioned2026-06-25T10:11:54Z
dc.date.available2026-06-25T10:11:54Z
dc.date.issued2026
dc.date.updated2026-06-25T09:58:07Z
dc.description.abstractLuciferins are a class of small, light-emitting molecules that produce visible light through an oxidation reaction catalysed by luciferase enzymes. This bioluminescent system, when combined with CCD camera technologies, has enabled groundbreaking advances in measuring mammalian gene expression, protein–protein interactions, biochemical labelling, and small molecule dynamics. Among the luciferins, D-luciferin—originally isolated from the American firefly Photinus pyralis—is the most extensively studied. Synthetic analogues of D-luciferin have become increasingly important due to their incorporation into a wide range of commercially available assay kits, where they serve as sensitive reporters in both in vitro and in vivo applications. This thesis focuses on the development of improved synthetic methods for D-thioluciferin, C6-substituted analogues, and aza-derivatives of D-luciferin, the latter enabling the design of novel caged bioluminescent probes for advanced molecular imaging.
dc.identifier.apacitationFredericks, M. (2026). <i>Synthesis and evaluation of bioluminescent probes as tools for anticancer drug discovery</i>. (). University of Cape Town ,Faculty of Science ,Department of Chemistry. Retrieved from http://hdl.handle.net/11427/43385en_ZA
dc.identifier.chicagocitationFredericks, Maryam. <i>"Synthesis and evaluation of bioluminescent probes as tools for anticancer drug discovery."</i> ., University of Cape Town ,Faculty of Science ,Department of Chemistry, 2026. http://hdl.handle.net/11427/43385en_ZA
dc.identifier.citationFredericks, M. 2026. Synthesis and evaluation of bioluminescent probes as tools for anticancer drug discovery. . University of Cape Town ,Faculty of Science ,Department of Chemistry. http://hdl.handle.net/11427/43385en_ZA
dc.identifier.ris TY - Thesis / Dissertation AU - Fredericks, Maryam AB - Luciferins are a class of small, light-emitting molecules that produce visible light through an oxidation reaction catalysed by luciferase enzymes. This bioluminescent system, when combined with CCD camera technologies, has enabled groundbreaking advances in measuring mammalian gene expression, protein–protein interactions, biochemical labelling, and small molecule dynamics. Among the luciferins, D-luciferin—originally isolated from the American firefly Photinus pyralis—is the most extensively studied. Synthetic analogues of D-luciferin have become increasingly important due to their incorporation into a wide range of commercially available assay kits, where they serve as sensitive reporters in both in vitro and in vivo applications. This thesis focuses on the development of improved synthetic methods for D-thioluciferin, C6-substituted analogues, and aza-derivatives of D-luciferin, the latter enabling the design of novel caged bioluminescent probes for advanced molecular imaging. DA - 2026 DB - OpenUCT DP - University of Cape Town KW - bioluminescent probes KW - drug LK - https://open.uct.ac.za PB - University of Cape Town PY - 2026 T1 - Synthesis and evaluation of bioluminescent probes as tools for anticancer drug discovery TI - Synthesis and evaluation of bioluminescent probes as tools for anticancer drug discovery UR - http://hdl.handle.net/11427/43385 ER - en_ZA
dc.identifier.urihttp://hdl.handle.net/11427/43385
dc.identifier.vancouvercitationFredericks M. Synthesis and evaluation of bioluminescent probes as tools for anticancer drug discovery. []. University of Cape Town ,Faculty of Science ,Department of Chemistry, 2026 [cited yyyy month dd]. Available from: http://hdl.handle.net/11427/43385en_ZA
dc.language.isoen
dc.language.rfc3066eng
dc.publisher.departmentDepartment of Chemistry
dc.publisher.facultyFaculty of Science
dc.publisher.institutionUniversity of Cape Town
dc.subjectbioluminescent probes
dc.subjectdrug
dc.titleSynthesis and evaluation of bioluminescent probes as tools for anticancer drug discovery
dc.typeThesis / Dissertation
dc.type.qualificationlevelMasters
dc.type.qualificationlevelMSc
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