[1,2-Bis(diphenylphosphino)ethane]-diiodidoplatinum(II) dichloromethane disolvate

Journal Article

2007

Permanent link to this Item
http://hdl.handle.net/11427/25909
Files
Sivaramakrishna_Article_2007.pdf (287.54 KB)
Authors
Sivaramakrishna, Akella
Su, Hong
Moss, John R
Journal Title

Acta Crystallographica Section E-Structure Reports Online

Link to Journal
http://journals.iucr.org/e/
Journal ISSN
Volume Title
Publisher
Publisher

University of Cape Town

Department
Department of Chemistry
Faculty
Faculty of Science
License
Series
Abstract
In the title compound, [PtI2(C26H24P2)]·2CH2Cl2, the PtI2(dppe) [dppe = 1,2-bis­(diphenyl­phosphino)ethane] mol­ecules possess twofold rotation symmetry. The Pt coordination displays a square-planar arrangement, with the sum of the angles around the Pt atom being 360.01 (2)°. The Pt-I distance is 2.6484 (5) Å. In the crystal structure, inter­molecular C-H...I contacts link the PtI2(dppe) mol­ecules into rows along the c axis, with a C...I distance of 3.873 (5) Å.
Description
Keywords
Chemistry

Reference:

Sivaramakrishna, A., Su, H., & Moss, J. R. (2007). [1, 2-Bis (diphenylphosphino) ethane] diiodidoplatinum (II) dichloromethane disolvate. Acta Crystallographica Section E: Structure Reports Online, 63(11), 2648-2648.

Collections
Journal Articles