Synthesis, characterization and evaluation of flourocarbon containing rhodium complexes for biphasic hydroformylation reactions

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dc.contributor.advisorSmith, Gregory Sen_ZA
dc.contributor.authorMaqeda, Latisaen_ZA
dc.date.accessioned2015-07-03T10:36:04Z
dc.date.available2015-07-03T10:36:04Z
dc.date.issued2014en_ZA
dc.descriptionIncludes bibliographical references.en_ZA
dc.description.abstractThe synthesis and characterization of fluorocarbon-containing salicylaldimine and iminophosphine ligands and their Rh(I) complexes is described. These ligands were obtained via a Schiff base condensation reaction between 2-diphenylphosphinobenzaldehyde and salicylaldehyde with the appropriate amines. The ligands were subsequently used to synthesize various Rh(I) complexes of the type [Rh(PN)Cl(CO)] and [Rh(NO)COD] from metal precursors [RhCl(CO)₂]₂ and [RhCl(COD)]₂ , respectively. The complexes were isolated as air stable solids.en_ZA
dc.identifier.apacitationMaqeda, L. (2014). <i>Synthesis, characterization and evaluation of flourocarbon containing rhodium complexes for biphasic hydroformylation reactions</i>. (Thesis). University of Cape Town ,Faculty of Science ,Department of Chemistry. Retrieved from http://hdl.handle.net/11427/13381en_ZA
dc.identifier.chicagocitationMaqeda, Latisa. <i>"Synthesis, characterization and evaluation of flourocarbon containing rhodium complexes for biphasic hydroformylation reactions."</i> Thesis., University of Cape Town ,Faculty of Science ,Department of Chemistry, 2014. http://hdl.handle.net/11427/13381en_ZA
dc.identifier.citationMaqeda, L. 2014. Synthesis, characterization and evaluation of flourocarbon containing rhodium complexes for biphasic hydroformylation reactions. University of Cape Town.en_ZA
dc.identifier.ris TY - Thesis / Dissertation AU - Maqeda, Latisa AB - The synthesis and characterization of fluorocarbon-containing salicylaldimine and iminophosphine ligands and their Rh(I) complexes is described. These ligands were obtained via a Schiff base condensation reaction between 2-diphenylphosphinobenzaldehyde and salicylaldehyde with the appropriate amines. The ligands were subsequently used to synthesize various Rh(I) complexes of the type [Rh(PN)Cl(CO)] and [Rh(NO)COD] from metal precursors [RhCl(CO)&#8322;]&#8322; and [RhCl(COD)]&#8322; , respectively. The complexes were isolated as air stable solids. DA - 2014 DB - OpenUCT DP - University of Cape Town LK - https://open.uct.ac.za PB - University of Cape Town PY - 2014 T1 - Synthesis, characterization and evaluation of flourocarbon containing rhodium complexes for biphasic hydroformylation reactions TI - Synthesis, characterization and evaluation of flourocarbon containing rhodium complexes for biphasic hydroformylation reactions UR - http://hdl.handle.net/11427/13381 ER - en_ZA
dc.identifier.urihttp://hdl.handle.net/11427/13381
dc.identifier.vancouvercitationMaqeda L. Synthesis, characterization and evaluation of flourocarbon containing rhodium complexes for biphasic hydroformylation reactions. [Thesis]. University of Cape Town ,Faculty of Science ,Department of Chemistry, 2014 [cited yyyy month dd]. Available from: http://hdl.handle.net/11427/13381en_ZA
dc.language.isoengen_ZA
dc.publisher.departmentDepartment of Chemistryen_ZA
dc.publisher.facultyFaculty of Scienceen_ZA
dc.publisher.institutionUniversity of Cape Town
dc.subject.otherChemistryen_ZA
dc.titleSynthesis, characterization and evaluation of flourocarbon containing rhodium complexes for biphasic hydroformylation reactionsen_ZA
dc.typeMaster Thesis
dc.type.qualificationlevelMasters
dc.type.qualificationnameMScen_ZA
uct.type.filetypeText
uct.type.filetypeImage
uct.type.publicationResearchen_ZA
uct.type.resourceThesisen_ZA
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