The removal of nitrogen and phosphorus in anoxic-aerobic digestion of waste activated sludge from biological nutrient removal systems

Master Thesis

2015

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University of Cape Town

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Biological nutrient removal (BNR) activated sludge systems (designed and operated with an additional function of biologically removing nitrogen and phosphorus) produce a waste activated sludge (WAS) that is rich in nitrogen (N) and phosphorus (P). When digested, this nitrogen and phosphorus are released, producing a dewatering liquor high in ammonia or nitrate and phosphate. Not only does this dewatering liquor need to be treated, but the phosphate also precipitates in the digester and surrounding pipework, resulting in loss of digester capacity and pipe blockages. This investigation studies anoxic-aerobic digestion (aerobic digestion with intermittent aeration), as an alternative digestion of BNR WAS. Aerobic digestion is simple to operate – being an extension of the activated sludge process, requiring aeration and limited recycling. This compared with anaerobic digestion which is complex to operate requiring airtight containers with fire risk, heating and much recycling. In anoxic-aerobic digestion, the nitrogen is removed by nitrification-denitrification, which has the added advantages of reducing the digester's oxygen demand and recovering some of the alkalinity lost in nitrification. Phosphate is precipitated in the digester - a convenient location. This results in a digester dewatering liquor low in nitrogen and phosphorus (<5 mgNH₄-N/l, <15 mgNO₃- N/l and 20 to 30 mgPO₄-P/l) that can be returned to the activated sludge plant without overloading it.
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