Determination of platinum, palladium and rhodium, in aqueous media by means of reversed phase-high performance liquid chromatography (RP-HPLC) after complexation with N,N-dialkyl-N'-acylthioureas
dc.contributor.advisor | Koch, Klaus | en_ZA |
dc.contributor.author | Mautjana, Nare Alpheus | en_ZA |
dc.date.accessioned | 2015-01-08T20:06:49Z | |
dc.date.available | 2015-01-08T20:06:49Z | |
dc.date.issued | 2000 | en_ZA |
dc.description | Includes bibliographical references. | en_ZA |
dc.description.abstract | The complexes were successfully separated using conventional Reversed Phase-High Performance Liquid Chromatography (RP-HPLC) and a UV detector. A simple method of complexation of platinum(II) and palladium(II) in acidic, aqueous samples was developed. This method involves the mixing of excess ligand (HL") in acetonitrile with aqueous solutions containing traces of platinum(II) and palladium(II) at room temperature followed by salt-induced phase separation prior to RP-HPLC analysis. In the case of rhodium(III), however, complexation was extremely slow and it has not been possible to include this metal in the complexation procedure for platinum(ll) and palladium(II). | en_ZA |
dc.identifier.apacitation | Mautjana, N. A. (2000). <i>Determination of platinum, palladium and rhodium, in aqueous media by means of reversed phase-high performance liquid chromatography (RP-HPLC) after complexation with N,N-dialkyl-N'-acylthioureas</i>. (Thesis). University of Cape Town ,Faculty of Science ,Department of Chemistry. Retrieved from http://hdl.handle.net/11427/11809 | en_ZA |
dc.identifier.chicagocitation | Mautjana, Nare Alpheus. <i>"Determination of platinum, palladium and rhodium, in aqueous media by means of reversed phase-high performance liquid chromatography (RP-HPLC) after complexation with N,N-dialkyl-N'-acylthioureas."</i> Thesis., University of Cape Town ,Faculty of Science ,Department of Chemistry, 2000. http://hdl.handle.net/11427/11809 | en_ZA |
dc.identifier.citation | Mautjana, N. 2000. Determination of platinum, palladium and rhodium, in aqueous media by means of reversed phase-high performance liquid chromatography (RP-HPLC) after complexation with N,N-dialkyl-N'-acylthioureas. University of Cape Town. | en_ZA |
dc.identifier.ris | TY - Thesis / Dissertation AU - Mautjana, Nare Alpheus AB - The complexes were successfully separated using conventional Reversed Phase-High Performance Liquid Chromatography (RP-HPLC) and a UV detector. A simple method of complexation of platinum(II) and palladium(II) in acidic, aqueous samples was developed. This method involves the mixing of excess ligand (HL") in acetonitrile with aqueous solutions containing traces of platinum(II) and palladium(II) at room temperature followed by salt-induced phase separation prior to RP-HPLC analysis. In the case of rhodium(III), however, complexation was extremely slow and it has not been possible to include this metal in the complexation procedure for platinum(ll) and palladium(II). DA - 2000 DB - OpenUCT DP - University of Cape Town LK - https://open.uct.ac.za PB - University of Cape Town PY - 2000 T1 - Determination of platinum, palladium and rhodium, in aqueous media by means of reversed phase-high performance liquid chromatography (RP-HPLC) after complexation with N,N-dialkyl-N'-acylthioureas TI - Determination of platinum, palladium and rhodium, in aqueous media by means of reversed phase-high performance liquid chromatography (RP-HPLC) after complexation with N,N-dialkyl-N'-acylthioureas UR - http://hdl.handle.net/11427/11809 ER - | en_ZA |
dc.identifier.uri | http://hdl.handle.net/11427/11809 | |
dc.identifier.vancouvercitation | Mautjana NA. Determination of platinum, palladium and rhodium, in aqueous media by means of reversed phase-high performance liquid chromatography (RP-HPLC) after complexation with N,N-dialkyl-N'-acylthioureas. [Thesis]. University of Cape Town ,Faculty of Science ,Department of Chemistry, 2000 [cited yyyy month dd]. Available from: http://hdl.handle.net/11427/11809 | en_ZA |
dc.language.iso | eng | en_ZA |
dc.publisher.department | Department of Chemistry | en_ZA |
dc.publisher.faculty | Faculty of Science | en_ZA |
dc.publisher.institution | University of Cape Town | |
dc.subject.other | Chemistry | en_ZA |
dc.title | Determination of platinum, palladium and rhodium, in aqueous media by means of reversed phase-high performance liquid chromatography (RP-HPLC) after complexation with N,N-dialkyl-N'-acylthioureas | en_ZA |
dc.type | Master Thesis | |
dc.type.qualificationlevel | Masters | |
dc.type.qualificationname | MSc | en_ZA |
uct.type.filetype | Text | |
uct.type.filetype | Image | |
uct.type.publication | Research | en_ZA |
uct.type.resource | Thesis | en_ZA |
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