Structures of Werner clathrates
| dc.contributor.advisor | Nassimben, Luigi | |
| dc.contributor.author | Bond, Dianne Ruth | |
| dc.date.accessioned | 2023-09-27T07:56:40Z | |
| dc.date.available | 2023-09-27T07:56:40Z | |
| dc.date.issued | 1982 | |
| dc.date.updated | 2023-09-27T07:44:19Z | |
| dc.description.abstract | The structures of two new Werner clathrates have been elucidated by X-ray diffraction. Ni(NCS) 2(c6 Hf) 2(c11ttgN) 2.methyl cello solve is monoclinic with a= 10,648(5), b = 23,005(12), a= 16,294(8).R, S = 98,04(2) 0 , Z = 4 and the space group C2/0 • The guest, methyl cello solve is disordered and lies at a centre of inversion. Ni(NCS) 2(c6 H7 N) 4.p-cymene is tetragonal with a= 17,105(9), b = 17, 105(9), a= 23,837(12).R, Z = 8 and the space group I4 1 fa• The guest, p-cymene is disordered and lies at a centre of inversion. The stoichiometry of the clathrates was investigated by various chemical methods including thermogravimetric analysis, differential thermal analysis, mass spectroscopy and proton nuclear magnetic resonance spectroscopy. Host-guest non-bonded energy relationships using atom-pair potentials are examined. Attempts have been made to estimate the association constants of sore of these computed in solution by proton nuclear magnetic resonance spectroscopy. | |
| dc.identifier.apacitation | Bond, D. R. (1982). <i>Structures of Werner clathrates</i>. (). ,Faculty of Science ,Department of Chemistry. Retrieved from http://hdl.handle.net/11427/38874 | en_ZA |
| dc.identifier.chicagocitation | Bond, Dianne Ruth. <i>"Structures of Werner clathrates."</i> ., ,Faculty of Science ,Department of Chemistry, 1982. http://hdl.handle.net/11427/38874 | en_ZA |
| dc.identifier.citation | Bond, D.R. 1982. Structures of Werner clathrates. . ,Faculty of Science ,Department of Chemistry. http://hdl.handle.net/11427/38874 | en_ZA |
| dc.identifier.ris | TY - Master Thesis AU - Bond, Dianne Ruth AB - The structures of two new Werner clathrates have been elucidated by X-ray diffraction. Ni(NCS) 2(c6 Hf) 2(c11ttgN) 2.methyl cello solve is monoclinic with a= 10,648(5), b = 23,005(12), a= 16,294(8).R, S = 98,04(2) 0 , Z = 4 and the space group C2/0 • The guest, methyl cello solve is disordered and lies at a centre of inversion. Ni(NCS) 2(c6 H7 N) 4.p-cymene is tetragonal with a= 17,105(9), b = 17, 105(9), a= 23,837(12).R, Z = 8 and the space group I4 1 fa• The guest, p-cymene is disordered and lies at a centre of inversion. The stoichiometry of the clathrates was investigated by various chemical methods including thermogravimetric analysis, differential thermal analysis, mass spectroscopy and proton nuclear magnetic resonance spectroscopy. Host-guest non-bonded energy relationships using atom-pair potentials are examined. Attempts have been made to estimate the association constants of sore of these computed in solution by proton nuclear magnetic resonance spectroscopy. DA - 1982 DB - OpenUCT DP - University of Cape Town KW - Werner clathraibs LK - https://open.uct.ac.za PY - 1982 T1 - ETD: Structures of Werner clathrates TI - ETD: Structures of Werner clathrates UR - http://hdl.handle.net/11427/38874 ER - | en_ZA |
| dc.identifier.uri | http://hdl.handle.net/11427/38874 | |
| dc.identifier.vancouvercitation | Bond DR. Structures of Werner clathrates. []. ,Faculty of Science ,Department of Chemistry, 1982 [cited yyyy month dd]. Available from: http://hdl.handle.net/11427/38874 | en_ZA |
| dc.language.rfc3066 | eng | |
| dc.publisher.department | Department of Chemistry | |
| dc.publisher.faculty | Faculty of Science | |
| dc.subject | Werner clathraibs | |
| dc.title | Structures of Werner clathrates | |
| dc.type | Master Thesis | |
| dc.type.qualificationlevel | Masters | |
| dc.type.qualificationlevel | MSc |