Groundwater redox conditions at a petroleum contaminated site, Kuils River, South Africa : pathways for BTEX biodegradation
Master Thesis
2003
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University of Cape Town
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Abstract
A shallow sandy aquifer, contaminated by petrol from an underground storage tank, was studied to determine if intrinsic bioremediation of the hydrocarbons is taking place. Groundwater samples taken from 32 monitoring wells were analysed for NO₃-,NH₄+, Mn²+, Fe²+, SO₄²-, and ΣH₂S. Portable electrodes were used to make field measurements of electrical conductivity, redox potential, and pH. The variation and distribution of these redox-sensitive groundwater constituents show that bioremediation via NO₃- reduction, Fe³+ reduction, and SO₄²- reduction (and possibly methanogenesis in the most reduced part of the plume) is occurring. In some cases redox processes are taking place simultaneously resulting in redox zones that overlap. Iron and sulphate reduction are the dominant processes taking place.
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Includes bibliographical references (leaves 84-88).
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Merrett, G. 2003. Groundwater redox conditions at a petroleum contaminated site, Kuils River, South Africa : pathways for BTEX biodegradation. University of Cape Town.