Synthesis, characterization, biological and catalytic studies of tridentate monothiosemicarbazone palladium (II) complexes

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dc.contributor.advisorSmith, Gregory Sen_ZA
dc.contributor.advisorChibale, Kellyen_ZA
dc.contributor.authorChellan, Prinessaen_ZA
dc.date.accessioned2014-08-13T14:26:00Z
dc.date.available2014-08-13T14:26:00Z
dc.date.issued2009en_ZA
dc.descriptionIncludes abstract.en_ZA
dc.descriptionIncludes bibliographical references.en_ZA
dc.description.abstractNine monothiosemicarbazone ligands were prepared by Schiff-base condensation reactions of thiosemicarbazide and the appropriate aryl aldehyde or ketone. These compounds were isolated as air- and moisture- stable solids and were characterized using NMR and IR spectroscopies, as well as mass spectrometry and elemental analysis in the case of ligand 3-terl.-butyl-2-hydroxy-benzaldehyde thiosemicarbazone, which is a new compound. Four of these ligands were reacted with precursors of type Pd(L)2CI2 yielding eight tridentate thiosemicarbazone Pd(II) complexes with general formula [Pd( 3-0,N,Sthiosemicarbazone)(L)] (L = PPh3 or 4-picoline). Six of these complexes are new compounds and were fully characterized using NMR and IR spectroscopies, mass spectrometry and elemental analysis. In addition, the solid state structures of three complexes were elucidated using single crystal X-ray diffraction methods.en_ZA
dc.identifier.apacitationChellan, P. (2009). <i>Synthesis, characterization, biological and catalytic studies of tridentate monothiosemicarbazone palladium (II) complexes</i>. (Thesis). University of Cape Town ,Faculty of Science ,Department of Chemistry. Retrieved from http://hdl.handle.net/11427/6297en_ZA
dc.identifier.chicagocitationChellan, Prinessa. <i>"Synthesis, characterization, biological and catalytic studies of tridentate monothiosemicarbazone palladium (II) complexes."</i> Thesis., University of Cape Town ,Faculty of Science ,Department of Chemistry, 2009. http://hdl.handle.net/11427/6297en_ZA
dc.identifier.citationChellan, P. 2009. Synthesis, characterization, biological and catalytic studies of tridentate monothiosemicarbazone palladium (II) complexes. University of Cape Town.en_ZA
dc.identifier.ris TY - Thesis / Dissertation AU - Chellan, Prinessa AB - Nine monothiosemicarbazone ligands were prepared by Schiff-base condensation reactions of thiosemicarbazide and the appropriate aryl aldehyde or ketone. These compounds were isolated as air- and moisture- stable solids and were characterized using NMR and IR spectroscopies, as well as mass spectrometry and elemental analysis in the case of ligand 3-terl.-butyl-2-hydroxy-benzaldehyde thiosemicarbazone, which is a new compound. Four of these ligands were reacted with precursors of type Pd(L)2CI2 yielding eight tridentate thiosemicarbazone Pd(II) complexes with general formula [Pd( 3-0,N,Sthiosemicarbazone)(L)] (L = PPh3 or 4-picoline). Six of these complexes are new compounds and were fully characterized using NMR and IR spectroscopies, mass spectrometry and elemental analysis. In addition, the solid state structures of three complexes were elucidated using single crystal X-ray diffraction methods. DA - 2009 DB - OpenUCT DP - University of Cape Town LK - https://open.uct.ac.za PB - University of Cape Town PY - 2009 T1 - Synthesis, characterization, biological and catalytic studies of tridentate monothiosemicarbazone palladium (II) complexes TI - Synthesis, characterization, biological and catalytic studies of tridentate monothiosemicarbazone palladium (II) complexes UR - http://hdl.handle.net/11427/6297 ER - en_ZA
dc.identifier.urihttp://hdl.handle.net/11427/6297
dc.identifier.vancouvercitationChellan P. Synthesis, characterization, biological and catalytic studies of tridentate monothiosemicarbazone palladium (II) complexes. [Thesis]. University of Cape Town ,Faculty of Science ,Department of Chemistry, 2009 [cited yyyy month dd]. Available from: http://hdl.handle.net/11427/6297en_ZA
dc.language.isoengen_ZA
dc.publisher.departmentDepartment of Chemistryen_ZA
dc.publisher.facultyFaculty of Scienceen_ZA
dc.publisher.institutionUniversity of Cape Town
dc.subject.otherChemistryen_ZA
dc.titleSynthesis, characterization, biological and catalytic studies of tridentate monothiosemicarbazone palladium (II) complexesen_ZA
dc.typeMaster Thesis
dc.type.qualificationlevelMasters
dc.type.qualificationnameMScen_ZA
uct.type.filetypeText
uct.type.filetypeImage
uct.type.publicationResearchen_ZA
uct.type.resourceThesisen_ZA
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