The synthesis, characterization and reactivity of metallacycloalkanes and their precursors

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dc.contributor.advisorMoss, John Ren_ZA
dc.contributor.advisorHutton, Alan Ten_ZA
dc.contributor.authorMadzivire, Cecilia Rutendoen_ZA
dc.date.accessioned2015-01-02T09:26:23Z
dc.date.available2015-01-02T09:26:23Z
dc.date.issued2010en_ZA
dc.descriptionIncludes abstract.en_ZA
dc.descriptionIncludes bibliographical references.en_ZA
dc.description.abstractA series of bis(alkenyl)platinum(II) complexes of the type [PtL2{(CH2)nCH=CH2h](L2 = 1 ,3-bis( diphenylphosphino )propane and n = 3-6) have been successfully synthesized and characterized by IH, I3C and 31p NMR spectroscopy, elemental analysis and mass spectrometry. I3C NMR data for these complexes is herein presented for the first time. A new route for the synthesis of dicarbonyldibromide rhenium complexCp*Re(CO)2Br2 affording the product in very high yields is also herein reported.en_ZA
dc.identifier.apacitationMadzivire, C. R. (2010). <i>The synthesis, characterization and reactivity of metallacycloalkanes and their precursors</i>. (Thesis). University of Cape Town ,Faculty of Science ,Department of Chemistry. Retrieved from http://hdl.handle.net/11427/11047en_ZA
dc.identifier.chicagocitationMadzivire, Cecilia Rutendo. <i>"The synthesis, characterization and reactivity of metallacycloalkanes and their precursors."</i> Thesis., University of Cape Town ,Faculty of Science ,Department of Chemistry, 2010. http://hdl.handle.net/11427/11047en_ZA
dc.identifier.citationMadzivire, C. 2010. The synthesis, characterization and reactivity of metallacycloalkanes and their precursors. University of Cape Town.en_ZA
dc.identifier.ris TY - Thesis / Dissertation AU - Madzivire, Cecilia Rutendo AB - A series of bis(alkenyl)platinum(II) complexes of the type [PtL2{(CH2)nCH=CH2h](L2 = 1 ,3-bis( diphenylphosphino )propane and n = 3-6) have been successfully synthesized and characterized by IH, I3C and 31p NMR spectroscopy, elemental analysis and mass spectrometry. I3C NMR data for these complexes is herein presented for the first time. A new route for the synthesis of dicarbonyldibromide rhenium complexCp*Re(CO)2Br2 affording the product in very high yields is also herein reported. DA - 2010 DB - OpenUCT DP - University of Cape Town LK - https://open.uct.ac.za PB - University of Cape Town PY - 2010 T1 - The synthesis, characterization and reactivity of metallacycloalkanes and their precursors TI - The synthesis, characterization and reactivity of metallacycloalkanes and their precursors UR - http://hdl.handle.net/11427/11047 ER - en_ZA
dc.identifier.urihttp://hdl.handle.net/11427/11047
dc.identifier.vancouvercitationMadzivire CR. The synthesis, characterization and reactivity of metallacycloalkanes and their precursors. [Thesis]. University of Cape Town ,Faculty of Science ,Department of Chemistry, 2010 [cited yyyy month dd]. Available from: http://hdl.handle.net/11427/11047en_ZA
dc.language.isoengen_ZA
dc.publisher.departmentDepartment of Chemistryen_ZA
dc.publisher.facultyFaculty of Scienceen_ZA
dc.publisher.institutionUniversity of Cape Town
dc.subject.otherChemistryen_ZA
dc.titleThe synthesis, characterization and reactivity of metallacycloalkanes and their precursorsen_ZA
dc.typeMaster Thesis
dc.type.qualificationlevelMasters
dc.type.qualificationnameMScen_ZA
uct.type.filetypeText
uct.type.filetypeImage
uct.type.publicationResearchen_ZA
uct.type.resourceThesisen_ZA
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