Synthesis, characterisation and reactivity studies of μ(α, ω)-alkanediyl complexes of ruthenium, iron and cobalt

Simple item page
dc.contributor.advisorMoss, John Ren_ZA
dc.contributor.advisorJackson, Graham Ellisen_ZA
dc.contributor.authorFinch, Karol Paulaen_ZA
dc.date.accessioned2016-09-25T16:52:20Z
dc.date.available2016-09-25T16:52:20Z
dc.date.issued1988en_ZA
dc.description.abstractThe new series of μ(α, ω)-alkanediyl compounds of ruthenium, [CpRu(CO)₂]₂[μ-(CH₂)ₙ], where n=5-10, have been prepared from Na[CpRu(CO)₂] and the corresponding diiodoalkane. These compounds, which are stable crystalline solids at ambient temperature, have been fully characterised by microanalysis, infrared, ¹H and ¹³C NMR spectroscopy, melting point and mass spectrometry. The new heterodinuclear complex [Cp(CO)₂Fe(CH₂)₄Ru(CO)₂Cp] has been synthesised by the reaction of [CpFe(CO)₂(CH₂)₄I] with Na[CpRu(CO)₂] and characterised by all the above mentioned techniques.en_ZA
dc.identifier.apacitationFinch, K. P. (1988). <i>Synthesis, characterisation and reactivity studies of μ(α, ω)-alkanediyl complexes of ruthenium, iron and cobalt</i>. (Thesis). University of Cape Town ,Faculty of Science ,Department of Chemistry. Retrieved from http://hdl.handle.net/11427/21938en_ZA
dc.identifier.chicagocitationFinch, Karol Paula. <i>"Synthesis, characterisation and reactivity studies of μ(α, ω)-alkanediyl complexes of ruthenium, iron and cobalt."</i> Thesis., University of Cape Town ,Faculty of Science ,Department of Chemistry, 1988. http://hdl.handle.net/11427/21938en_ZA
dc.identifier.citationFinch, K. 1988. Synthesis, characterisation and reactivity studies of μ(α, ω)-alkanediyl complexes of ruthenium, iron and cobalt. University of Cape Town.en_ZA
dc.identifier.ris TY - Thesis / Dissertation AU - Finch, Karol Paula AB - The new series of μ(α, ω)-alkanediyl compounds of ruthenium, [CpRu(CO)₂]₂[μ-(CH₂)ₙ], where n=5-10, have been prepared from Na[CpRu(CO)₂] and the corresponding diiodoalkane. These compounds, which are stable crystalline solids at ambient temperature, have been fully characterised by microanalysis, infrared, ¹H and ¹³C NMR spectroscopy, melting point and mass spectrometry. The new heterodinuclear complex [Cp(CO)₂Fe(CH₂)₄Ru(CO)₂Cp] has been synthesised by the reaction of [CpFe(CO)₂(CH₂)₄I] with Na[CpRu(CO)₂] and characterised by all the above mentioned techniques. DA - 1988 DB - OpenUCT DP - University of Cape Town LK - https://open.uct.ac.za PB - University of Cape Town PY - 1988 T1 - Synthesis, characterisation and reactivity studies of μ(α, ω)-alkanediyl complexes of ruthenium, iron and cobalt TI - Synthesis, characterisation and reactivity studies of μ(α, ω)-alkanediyl complexes of ruthenium, iron and cobalt UR - http://hdl.handle.net/11427/21938 ER - en_ZA
dc.identifier.urihttp://hdl.handle.net/11427/21938
dc.identifier.vancouvercitationFinch KP. Synthesis, characterisation and reactivity studies of μ(α, ω)-alkanediyl complexes of ruthenium, iron and cobalt. [Thesis]. University of Cape Town ,Faculty of Science ,Department of Chemistry, 1988 [cited yyyy month dd]. Available from: http://hdl.handle.net/11427/21938en_ZA
dc.language.isoengen_ZA
dc.publisher.departmentDepartment of Chemistryen_ZA
dc.publisher.facultyFaculty of Scienceen_ZA
dc.publisher.institutionUniversity of Cape Town
dc.subject.otherFischer-Tropsch processen_ZA
dc.subject.otherChemistryen_ZA
dc.titleSynthesis, characterisation and reactivity studies of μ(α, ω)-alkanediyl complexes of ruthenium, iron and cobalten_ZA
dc.typeMaster Thesis
dc.type.qualificationlevelMasters
dc.type.qualificationnameMScen_ZA
uct.type.filetypeText
uct.type.filetypeImage
uct.type.publicationResearchen_ZA
uct.type.resourceThesisen_ZA
Files
Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
thesis_sci_1988_finch_karol_paula.pdf
Size:
3.05 MB
Format:
Adobe Portable Document Format
Description:
Download
Collections
Masters