Determination of oxygen gas-liquid mass transfer rates in heap bioleach reactors

dc.contributor.authorPetersen, J
dc.date.accessioned2016-08-16T12:15:25Z
dc.date.available2016-08-16T12:15:25Z
dc.date.issued2010
dc.date.updated2016-08-16T12:13:41Z
dc.description.abstractA detailed experimental study is described which was conducted to determine the rate of oxygen gas–liquid mass transfer within the packed bed of heap bioleach reactors at different temperatures (22–68 °C), using the Na2SO3 method. The raw data was analysed using a simplified film mass transfer model, making corrections for oxygen solubility in concentrated solution and for increased water vapour partial pressure at elevated temperatures. The results compared favourably against two independent experimental leach studies, indicating kLa values between 33 and 46 h−1. The value varied with the particle size distribution of the packing, with kLa assuming larger values for those packings that had a higher fines contents. While kLa increases with temperature, the solubility of oxygen decreases simultaneously, resulting in net mass transfer rates being relatively unaffected by temperature in the range studied. This indicates that thermophile heap bioleach reactors are likely to operate under gas–liquid mass transfer limitations, especially at high altitude.en_ZA
dc.identifierhttp://dx.doi.org/10.1016/j.mineng.2010.01.006
dc.identifier.apacitationPetersen, J. (2010). Determination of oxygen gas-liquid mass transfer rates in heap bioleach reactors. <i> Minerals Engineering</i>, http://hdl.handle.net/11427/21272en_ZA
dc.identifier.chicagocitationPetersen, J "Determination of oxygen gas-liquid mass transfer rates in heap bioleach reactors." <i> Minerals Engineering</i> (2010) http://hdl.handle.net/11427/21272en_ZA
dc.identifier.citationPetersen, J. (2010). Determination of oxygen gas–liquid mass transfer rates in heap bioleach reactors. Minerals Engineering, 23(6), 504-510.en_ZA
dc.identifier.issn0892-6875en_ZA
dc.identifier.ris TY - Journal Article AU - Petersen, J AB - A detailed experimental study is described which was conducted to determine the rate of oxygen gas–liquid mass transfer within the packed bed of heap bioleach reactors at different temperatures (22–68 °C), using the Na2SO3 method. The raw data was analysed using a simplified film mass transfer model, making corrections for oxygen solubility in concentrated solution and for increased water vapour partial pressure at elevated temperatures. The results compared favourably against two independent experimental leach studies, indicating kLa values between 33 and 46 h−1. The value varied with the particle size distribution of the packing, with kLa assuming larger values for those packings that had a higher fines contents. While kLa increases with temperature, the solubility of oxygen decreases simultaneously, resulting in net mass transfer rates being relatively unaffected by temperature in the range studied. This indicates that thermophile heap bioleach reactors are likely to operate under gas–liquid mass transfer limitations, especially at high altitude. DA - 2010 DB - OpenUCT DP - University of Cape Town J1 -  Minerals Engineering LK - https://open.uct.ac.za PB - University of Cape Town PY - 2010 SM - 0892-6875 T1 - Determination of oxygen gas-liquid mass transfer rates in heap bioleach reactors TI - Determination of oxygen gas-liquid mass transfer rates in heap bioleach reactors UR - http://hdl.handle.net/11427/21272 ER - en_ZA
dc.identifier.urihttp://hdl.handle.net/11427/21272
dc.identifier.urihttp://www.sciencedirect.com/science/article/pii/S0892687510000075
dc.identifier.vancouvercitationPetersen J. Determination of oxygen gas-liquid mass transfer rates in heap bioleach reactors.  Minerals Engineering. 2010; http://hdl.handle.net/11427/21272.en_ZA
dc.languageengen_ZA
dc.publisherElsevieren_ZA
dc.publisher.institutionUniversity of Cape Town
dc.source Minerals Engineeringen_ZA
dc.source.urihttp://www.sciencedirect.com/science/journal/08926875
dc.subject.otherLeaching
dc.subject.otherHeap leaching
dc.subject.otherBio-leaching
dc.subject.otherOxygen
dc.subject.otherGas–liquid mass transfer
dc.titleDetermination of oxygen gas-liquid mass transfer rates in heap bioleach reactorsen_ZA
dc.typeJournal Articleen_ZA
uct.type.filetypeText
uct.type.filetypeImage
uct.type.publicationResearchen_ZA
uct.type.resourceArticleen_ZA
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