The synthesis, characterization and decomposition studies of novel palladacycloalkanes and their precursors

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dc.contributor.advisorMoss, John Ren_ZA
dc.contributor.advisorSmith, Gregoryen_ZA
dc.contributor.authorMahamo, Tebelloen_ZA
dc.date.accessioned2014-08-13T14:26:57Z
dc.date.available2014-08-13T14:26:57Z
dc.date.issued2007en_ZA
dc.descriptionIncludes bibliographical references (leaf 100).en_ZA
dc.description.abstractThe synthesis and characterization of palladacycloheptane and palladacyclononane complexes based on 1,5-cyclooctadiene (COD), 2,2'bipyridine (bipy), triphenylphosphine (PPh3), and 1,2-bis(diphenylphosphino)ethane (dppe), and their precursors were successfully carried out. The complexes were characterized by 1H, 13C and 31p NMR spectroscopy, mass spectrometry as well as elemental analysis. The palladacycloalkanes were prepared from the bis(alkenyl) complexes of the type cis-[Pd{(CH2)nCH=CH2hL21 (n = 2, 3; L = PPh3; L2 = COD, bipy, dppe) by ring closing metathesis (RCM) reactions followed by hydrogenation.en_ZA
dc.identifier.apacitationMahamo, T. (2007). <i>The synthesis, characterization and decomposition studies of novel palladacycloalkanes and their precursors</i>. (Thesis). University of Cape Town ,Faculty of Science ,Department of Chemistry. Retrieved from http://hdl.handle.net/11427/6328en_ZA
dc.identifier.chicagocitationMahamo, Tebello. <i>"The synthesis, characterization and decomposition studies of novel palladacycloalkanes and their precursors."</i> Thesis., University of Cape Town ,Faculty of Science ,Department of Chemistry, 2007. http://hdl.handle.net/11427/6328en_ZA
dc.identifier.citationMahamo, T. 2007. The synthesis, characterization and decomposition studies of novel palladacycloalkanes and their precursors. University of Cape Town.en_ZA
dc.identifier.ris TY - Thesis / Dissertation AU - Mahamo, Tebello AB - The synthesis and characterization of palladacycloheptane and palladacyclononane complexes based on 1,5-cyclooctadiene (COD), 2,2'bipyridine (bipy), triphenylphosphine (PPh3), and 1,2-bis(diphenylphosphino)ethane (dppe), and their precursors were successfully carried out. The complexes were characterized by 1H, 13C and 31p NMR spectroscopy, mass spectrometry as well as elemental analysis. The palladacycloalkanes were prepared from the bis(alkenyl) complexes of the type cis-[Pd{(CH2)nCH=CH2hL21 (n = 2, 3; L = PPh3; L2 = COD, bipy, dppe) by ring closing metathesis (RCM) reactions followed by hydrogenation. DA - 2007 DB - OpenUCT DP - University of Cape Town LK - https://open.uct.ac.za PB - University of Cape Town PY - 2007 T1 - The synthesis, characterization and decomposition studies of novel palladacycloalkanes and their precursors TI - The synthesis, characterization and decomposition studies of novel palladacycloalkanes and their precursors UR - http://hdl.handle.net/11427/6328 ER - en_ZA
dc.identifier.urihttp://hdl.handle.net/11427/6328
dc.identifier.vancouvercitationMahamo T. The synthesis, characterization and decomposition studies of novel palladacycloalkanes and their precursors. [Thesis]. University of Cape Town ,Faculty of Science ,Department of Chemistry, 2007 [cited yyyy month dd]. Available from: http://hdl.handle.net/11427/6328en_ZA
dc.language.isoengen_ZA
dc.publisher.departmentDepartment of Chemistryen_ZA
dc.publisher.facultyFaculty of Scienceen_ZA
dc.publisher.institutionUniversity of Cape Town
dc.subject.otherChemistryen_ZA
dc.titleThe synthesis, characterization and decomposition studies of novel palladacycloalkanes and their precursorsen_ZA
dc.typeMaster Thesis
dc.type.qualificationlevelMasters
dc.type.qualificationnameMScen_ZA
uct.type.filetypeText
uct.type.filetypeImage
uct.type.publicationResearchen_ZA
uct.type.resourceThesisen_ZA
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