Browsing by Subject "Chichibabin synthesis"

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    Sydnone C-4 heteroarylation with an indolizine ring via Chichibabin indolizine synthesis
    (2016) Albota, Florin; Caira, Mino R; Draghici, Constantin; Dumitrascu, Florea; Dumitrescu, Denisa E
    The synthesis of sydnones heteroarylated at C-4 with an indolizine was achieved by Chichibabin (Tschitschibabin) indolizine synthesis starting from the corresponding sydnone-N-pyridinium bromides. The latter compounds were also transformed to sydnone-indolizines connected through a keto group at the C-4 position by refluxing them in 1,2-epoxybutane with an activated alkyne. The structures of the new compounds were assigned by FTIR, NMR spectroscopy and X-ray analysis.