Inclusion compounds : structure, reactivity and selectivity

 

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dc.contributor.advisor Nassimbeni, Luigi R en_ZA
dc.contributor.author Su, Hong en_ZA
dc.date.accessioned 2014-11-22T05:52:53Z
dc.date.available 2014-11-22T05:52:53Z
dc.date.issued 2002 en_ZA
dc.identifier.citation Su, H. 2002. Inclusion compounds : structure, reactivity and selectivity. University of Cape Town. en_ZA
dc.identifier.uri http://hdl.handle.net/11427/9783
dc.description Includes bibliographical references. en_ZA
dc.description.abstract This thesis is concerned with structure, thermodynamic and kinetic aspects of a variety of inclusion compounds which contain small organic guests. The host compounds studied are alkaline-earth metal salts of O,O’-dibenzoyl-(2R, 3R)-tartraric acid (magnesium, calcium and strontium), 1,1’-bis-(4-hydroxyphenyl)cyclohexane (DHPC) and 2,2’-dihydroxy-1,1’-binaphthyl (BINAP). The alkaline-earth metal salts form coordination complexes with 2-methoxyethanol, water or ethanol and the guests act as a part of the coordination sphere of the metal ions. The diol host DHPC preferably forms layer type inclusion compounds with the isomers of picoline, lutidine and xylidine, as well as a number of selected solvents including 1,4-dioxane, DMSO, morpholine, THF and acetone, preferably in channel type inclusion modes. In the latter two classes of inclusion compounds the inclusion is facilitated by the formation of hydrogen bonds from the host hydroxyl moieties to the guests. en_ZA
dc.language.iso eng en_ZA
dc.subject.other Chemistry en_ZA
dc.title Inclusion compounds : structure, reactivity and selectivity en_ZA
dc.type Doctoral Thesis
uct.type.publication Research en_ZA
uct.type.resource Thesis en_ZA
dc.publisher.institution University of Cape Town
dc.publisher.faculty Faculty of Science en_ZA
dc.publisher.department Department of Chemistry en_ZA
dc.type.qualificationlevel Doctoral
dc.type.qualificationname PhD en_ZA
uct.type.filetype Text
uct.type.filetype Image
dc.identifier.apacitation Su, H. (2002). <i>Inclusion compounds : structure, reactivity and selectivity</i>. (Thesis). University of Cape Town ,Faculty of Science ,Department of Chemistry. Retrieved from http://hdl.handle.net/11427/9783 en_ZA
dc.identifier.chicagocitation Su, Hong. <i>"Inclusion compounds : structure, reactivity and selectivity."</i> Thesis., University of Cape Town ,Faculty of Science ,Department of Chemistry, 2002. http://hdl.handle.net/11427/9783 en_ZA
dc.identifier.vancouvercitation Su H. Inclusion compounds : structure, reactivity and selectivity. [Thesis]. University of Cape Town ,Faculty of Science ,Department of Chemistry, 2002 [cited yyyy month dd]. Available from: http://hdl.handle.net/11427/9783 en_ZA
dc.identifier.ris TY - Thesis / Dissertation AU - Su, Hong AB - This thesis is concerned with structure, thermodynamic and kinetic aspects of a variety of inclusion compounds which contain small organic guests. The host compounds studied are alkaline-earth metal salts of O,O’-dibenzoyl-(2R, 3R)-tartraric acid (magnesium, calcium and strontium), 1,1’-bis-(4-hydroxyphenyl)cyclohexane (DHPC) and 2,2’-dihydroxy-1,1’-binaphthyl (BINAP). The alkaline-earth metal salts form coordination complexes with 2-methoxyethanol, water or ethanol and the guests act as a part of the coordination sphere of the metal ions. The diol host DHPC preferably forms layer type inclusion compounds with the isomers of picoline, lutidine and xylidine, as well as a number of selected solvents including 1,4-dioxane, DMSO, morpholine, THF and acetone, preferably in channel type inclusion modes. In the latter two classes of inclusion compounds the inclusion is facilitated by the formation of hydrogen bonds from the host hydroxyl moieties to the guests. DA - 2002 DB - OpenUCT DP - University of Cape Town LK - https://open.uct.ac.za PB - University of Cape Town PY - 2002 T1 - Inclusion compounds : structure, reactivity and selectivity TI - Inclusion compounds : structure, reactivity and selectivity UR - http://hdl.handle.net/11427/9783 ER - en_ZA


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