Progressive design and self-assembly of supramolecular architectures : based on metallamacrocyclic nickel(II) complexes with bipodal tetra-alkylaroylbis (thioureas)

 

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dc.contributor.advisor Bourne, Susan A en_ZA
dc.contributor.advisor Koch, Klaus en_ZA
dc.contributor.author Hallale, Oren en_ZA
dc.date.accessioned 2014-08-13T14:26:24Z
dc.date.available 2014-08-13T14:26:24Z
dc.date.issued 2004 en_ZA
dc.identifier.citation Hallale, O. 2004. Progressive design and self-assembly of supramolecular architectures : based on metallamacrocyclic nickel(II) complexes with bipodal tetra-alkylaroylbis (thioureas). University of Cape Town. en_ZA
dc.identifier.uri http://hdl.handle.net/11427/6310
dc.description Includes bibliographical references. en_ZA
dc.description.abstract Rationally designed bipodal3,3,3',3'-tetraalkyl-l,1'-benzoylbis(thioureas) are used as pre-programmed cheiating ligands to form metallamacrocyclic square planar nickel(ll) complexes via self-assembly. Metal : ligand stoichiometries of either 2:2 or 3:3 can be achieved by using meta- or para- substituted ligands. The metallamacrocyclic complexes are subsequently converted into octahedral adducts via the addition of monodentate nitrogen donor ligands. Metallamacrocycles are further employed as secondary building units in the self-assembly of I-dimensional double- or tripleconnected coordination polymers. The synthesis of these polymers is achieved with the use of exo-bidentate nitrogen donor ligands. en_ZA
dc.language.iso eng en_ZA
dc.subject.other Chemistry en_ZA
dc.title Progressive design and self-assembly of supramolecular architectures : based on metallamacrocyclic nickel(II) complexes with bipodal tetra-alkylaroylbis (thioureas) en_ZA
dc.type Doctoral Thesis
uct.type.publication Research en_ZA
uct.type.resource Thesis en_ZA
dc.publisher.institution University of Cape Town
dc.publisher.faculty Faculty of Science en_ZA
dc.publisher.department Department of Chemistry en_ZA
dc.type.qualificationlevel Doctoral
dc.type.qualificationname PhD en_ZA
uct.type.filetype Text
uct.type.filetype Image
dc.identifier.apacitation Hallale, O. (2004). <i>Progressive design and self-assembly of supramolecular architectures : based on metallamacrocyclic nickel(II) complexes with bipodal tetra-alkylaroylbis (thioureas)</i>. (Thesis). University of Cape Town ,Faculty of Science ,Department of Chemistry. Retrieved from http://hdl.handle.net/11427/6310 en_ZA
dc.identifier.chicagocitation Hallale, Oren. <i>"Progressive design and self-assembly of supramolecular architectures : based on metallamacrocyclic nickel(II) complexes with bipodal tetra-alkylaroylbis (thioureas)."</i> Thesis., University of Cape Town ,Faculty of Science ,Department of Chemistry, 2004. http://hdl.handle.net/11427/6310 en_ZA
dc.identifier.vancouvercitation Hallale O. Progressive design and self-assembly of supramolecular architectures : based on metallamacrocyclic nickel(II) complexes with bipodal tetra-alkylaroylbis (thioureas). [Thesis]. University of Cape Town ,Faculty of Science ,Department of Chemistry, 2004 [cited yyyy month dd]. Available from: http://hdl.handle.net/11427/6310 en_ZA
dc.identifier.ris TY - Thesis / Dissertation AU - Hallale, Oren AB - Rationally designed bipodal3,3,3',3'-tetraalkyl-l,1'-benzoylbis(thioureas) are used as pre-programmed cheiating ligands to form metallamacrocyclic square planar nickel(ll) complexes via self-assembly. Metal : ligand stoichiometries of either 2:2 or 3:3 can be achieved by using meta- or para- substituted ligands. The metallamacrocyclic complexes are subsequently converted into octahedral adducts via the addition of monodentate nitrogen donor ligands. Metallamacrocycles are further employed as secondary building units in the self-assembly of I-dimensional double- or tripleconnected coordination polymers. The synthesis of these polymers is achieved with the use of exo-bidentate nitrogen donor ligands. DA - 2004 DB - OpenUCT DP - University of Cape Town LK - https://open.uct.ac.za PB - University of Cape Town PY - 2004 T1 - Progressive design and self-assembly of supramolecular architectures : based on metallamacrocyclic nickel(II) complexes with bipodal tetra-alkylaroylbis (thioureas) TI - Progressive design and self-assembly of supramolecular architectures : based on metallamacrocyclic nickel(II) complexes with bipodal tetra-alkylaroylbis (thioureas) UR - http://hdl.handle.net/11427/6310 ER - en_ZA


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