Syntheses related to the preparation of substituted glycosyl derivates of pyrrolo (3,2-f) quinolines : spectroscopic studies of acetylated glycosylamine derivatives

 

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dc.contributor.advisor Stephen, A M en_ZA
dc.contributor.author Magnin, Anthony Alan en_ZA
dc.date.accessioned 2016-03-21T19:25:05Z
dc.date.available 2016-03-21T19:25:05Z
dc.date.issued 1970 en_ZA
dc.identifier.citation Magnin, A. 1970. Syntheses related to the preparation of substituted glycosyl derivates of pyrrolo (3,2-f) quinolines : spectroscopic studies of acetylated glycosylamine derivatives. University of Cape Town. en_ZA
dc.identifier.uri http://hdl.handle.net/11427/18114
dc.description.abstract The synthesis of 25 acetylated glycopyranosylamine derivatives (15 of which are newly reported here) from substituted sugar derivatives and amines is described. Eleven different methods were employed in these syntheses. Of the compounds prepared, 15 are substituted glycosylindoline derivatives. The stereospecific synthesis of 1-(2,3,4,6-tetra-0-acetyl-β-D-glucopyranosyl)indoline from 3,4,6-tri-0-acetyl-α-D-glucopyranose l,2-(ethyl orthoacetate) and indoline is reported for the first time. The dehydrogenation of 10 substituted glycopyranosylindoline derivatives to the corresponding glycopyranosylindole derivatives (of which 7 are newly reported) by two methods, is described. en_ZA
dc.language.iso eng en_ZA
dc.subject.other Chemistry en_ZA
dc.title Syntheses related to the preparation of substituted glycosyl derivates of pyrrolo (3,2-f) quinolines : spectroscopic studies of acetylated glycosylamine derivatives en_ZA
dc.type Doctoral Thesis
uct.type.publication Research en_ZA
uct.type.resource Thesis en_ZA
dc.publisher.institution University of Cape Town
dc.publisher.faculty Faculty of Science en_ZA
dc.publisher.department Department of Chemistry en_ZA
dc.type.qualificationlevel Doctoral
dc.type.qualificationname PhD en_ZA
uct.type.filetype Text
uct.type.filetype Image
dc.identifier.apacitation Magnin, A. A. (1970). <i>Syntheses related to the preparation of substituted glycosyl derivates of pyrrolo (3,2-f) quinolines : spectroscopic studies of acetylated glycosylamine derivatives</i>. (Thesis). University of Cape Town ,Faculty of Science ,Department of Chemistry. Retrieved from http://hdl.handle.net/11427/18114 en_ZA
dc.identifier.chicagocitation Magnin, Anthony Alan. <i>"Syntheses related to the preparation of substituted glycosyl derivates of pyrrolo (3,2-f) quinolines : spectroscopic studies of acetylated glycosylamine derivatives."</i> Thesis., University of Cape Town ,Faculty of Science ,Department of Chemistry, 1970. http://hdl.handle.net/11427/18114 en_ZA
dc.identifier.vancouvercitation Magnin AA. Syntheses related to the preparation of substituted glycosyl derivates of pyrrolo (3,2-f) quinolines : spectroscopic studies of acetylated glycosylamine derivatives. [Thesis]. University of Cape Town ,Faculty of Science ,Department of Chemistry, 1970 [cited yyyy month dd]. Available from: http://hdl.handle.net/11427/18114 en_ZA
dc.identifier.ris TY - Thesis / Dissertation AU - Magnin, Anthony Alan AB - The synthesis of 25 acetylated glycopyranosylamine derivatives (15 of which are newly reported here) from substituted sugar derivatives and amines is described. Eleven different methods were employed in these syntheses. Of the compounds prepared, 15 are substituted glycosylindoline derivatives. The stereospecific synthesis of 1-(2,3,4,6-tetra-0-acetyl-β-D-glucopyranosyl)indoline from 3,4,6-tri-0-acetyl-α-D-glucopyranose l,2-(ethyl orthoacetate) and indoline is reported for the first time. The dehydrogenation of 10 substituted glycopyranosylindoline derivatives to the corresponding glycopyranosylindole derivatives (of which 7 are newly reported) by two methods, is described. DA - 1970 DB - OpenUCT DP - University of Cape Town LK - https://open.uct.ac.za PB - University of Cape Town PY - 1970 T1 - Syntheses related to the preparation of substituted glycosyl derivates of pyrrolo (3,2-f) quinolines : spectroscopic studies of acetylated glycosylamine derivatives TI - Syntheses related to the preparation of substituted glycosyl derivates of pyrrolo (3,2-f) quinolines : spectroscopic studies of acetylated glycosylamine derivatives UR - http://hdl.handle.net/11427/18114 ER - en_ZA


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