Non-maximum entropy polymer elasticity, viscoelasticity and the lattice Boltzmann method

Doctoral Thesis

2010

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University of Cape Town

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Abstract
Various models of viscoelasticity exist based on continuum mechanics. In this work a statistical mechanical approach is taken to derive a new isotropic, hyperelastic, viscoelastic, incompressible constitutive equation for polymers. The result has been achieved by generating a novel physics for the microscopic behaviour of polymers. A vocabulary has been created to facilitate the physics. A new differential equation describing polymer behaviour is derived based on the mathematical description of the physics.
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Includes bibliographical references (p. 291-303).

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