Browsing by Author "Barnett, Christopher Bevan"

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Developing methods to construct ring pucker free energy hypersurfaces applied to the analysis of glycosidase enzyme catalytic mechanisms

Author: Barnett, Christopher Bevan Date: 2010 Carbohydrates consist of one or more sub-units usually various 5- and 6-membered cycles (furanoses and pyranoses) which can twist, bend or flip into a variety of conformers that differ in strain - this is ring puckering. These puckers notably ... Read more
Electronic and solvent effects on monosaccharide conformations

Author: Barnett, Christopher Bevan Date: 2007 The hydroxymethyl group rotational preferences of the monosaccharides glucose and galactose are different from each other and non-intuitive (from a steric point of view) in their preferences for gauche conformers. These molecules exhibit very ... Read more

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