Browsing by Author "Dry, M"

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    Aromatization of 1-hexene and 1-octene by gallium/H-ZSM-5 catalysts.
    (Elsevier, 1996) Nash, R; Dry, M; O'Connor, C
    Gallium/H-ZSM-5 zeolite catalysts were tested for the aromatization of long-chain alkenes, namely 1-hexene and 1-octene. Aromatic yields of ca. 70% were obtained, which are similar to those reported in the literature for propene aromatization. The catalysts tested were prepared by impregnation by incipient wetness of gallium nitrate, ion-exchange with gallium nitrate and by physical mixing with β-gallium oxide crystallites. Hydrogen pretreatment improved the selectivity to aromatic products of gallium/H-ZSM-5 catalysts prepared by physical mixing with β-gallium oxide, but decreased aromatic selectivity for catalysts prepared by ion-exchange and impregnation.
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    Influence of preparation variables on the dispersion of platinum on zeolite KL.
    (Elsevier, 1997) M'Kombe, C; Dry, M; O'Connor, C
    Various preparation conditions were investigated to evaluate their effect on the dispersion of Pt on zeolite KL. The highest dispersion was obtained by calcining in O2 at about 350 °C. Calcining in N2 or H2 resulted in lower dispersions. Irrespective of the gas atmosphere, heating at 600 °C resulted in sintering of the Pt. The duration of calcination, whether at 350 °C or 600 °C, had little effect on Pt dispersion. The rate at which the temperature was increased up to the calcination temperature and the rate of the O2 flow also had no effect. Subsequent to identical calcination procedures, reduction with H2 resulted in much higher Pt dispersions than reduction with CO. Below 350 °C the temperature of the H2 reduction did not have a marked effect on dispersion. At the 1.5% Pt level, different loading techniques, viz., liquid ion exchange, solid-state ion exchange, and incipient wetness impregnation, resulted in similar Pt dispersions. There was a good correlation between the percentage of Pt dispersion and n-hexane conversion in the aromatization reaction. Pt dispersions were determined by CO chemisorption, and the observed trends were confirmed by TEM. Hydrogen chemisorption was a less satisfactory method of measuring dispersion. © Elsevier Science Inc. 1997