Browsing by Author "Corin, Kirsten Claire"

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    Separation by enclathration
    (2006) Corin, Kirsten Claire
    In this thesis the inclusion properties of the host compounds, 9,9'-(1,4-Phenylene)bis(fluoren-9-ol) (WEB9) and 1, 1,2,2-tetraphenyl-1,2-ethane diol (TPED) were investigated. These host compounds are large, bulky and rigid, they contain functionality that allows them to selectively interact with other molecules, such as the chosen guests in this work. Such host···guest interactions are the central topic under study. The host molecules form inclusion complexes with small organic guest molecules. The host TPED complexes with the guests; 2-picoline, 3-picoline, 4-picoline, toluene, chlorobenzene, bromobenzene, iodobenzene, dioxane, morpholine, piperazine and pyridine. It was used in the two-component separation of dioxane and morpholine, in the two- and three-component separation of the isomers of picoline as well as in the two-, three- and four-component separation of toluene and the halo-substituted benzenes. Along with the isomers of picoline, the effects of adding a neutral solvent as well as changing crystallization temperature were investigated. The host WEB9 complexes with the guests; aniline, benzylamine, 2-phenylethylamine, (S)-methylbenzylamine, (R,S)-methylbenzylamine, pyridine, 2-picoline, 3-picoline, 4-picoline, dioxane, morpholine and p-xylene. It was used in the two-component separation of aniline and benzylamine, in which the effect of a pH change was investigated. The structures of the complexes were elucidated using single crystal X-ray diffraction. Thermal analysis was performed in order to determine the thermal character of the complex, including techniques such as thermogravimetry, differential thermal analysis, hot stage microscopy and differential scanning calorimetry. The kinetics of enclathration of certain guests in the vapour phase were investigated using an automated magnetic suspension balance. The interaction potential of a series of guests was determined by packed column gas chromatography, in which a column was partially packed with either of the two host compounds and guests were passed through it. Competition experiments were performed to determine the selectivity of a host for a series of related guests. These experiments were initially conducted between pairs of guests and then later expanded to three- and four-component systems. The effect of changing the conditions of the competition experiment were investigated by; changing the pH, adding a neutral solvent as well as changing the temperature of crystallization.
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    The Electrochemical Response of Chalcopyrite and Galena to Degrading Water Quality
    (2022-11-21) Ndamase, Nolihle; Tadie, Margreth; Corin, Kirsten Claire
    Water is used as a liquid medium as well as a means of transportation during mining operations. Flotation, in particular, is a water intensive process where water makes up about 80–85% of the pulp phase. Process water contains organic and inorganic species which accumulate as they are recycled. To avoid the treatment costs of removing these contaminants, many mining operations allow the quality of their water to degrade over time. When this water is introduced into flotation circuits, the pulp chemistry is altered. Ionic species that accumulate in recycled process water have been shown by previous studies to be especially deleterious to flotation performance. Such ions include Ca2+, Cu2+, Mg2+, Pb2+, SO42− and S2O32−, amongst others. The flotation sub-process of collector adsorption which is responsible for inducing hydrophobicity on valuable mineral surfaces may be influenced by water chemistry. Accumulating ionic species have been shown to hinder collector adsorption which may reduce recovery of valuable minerals to the concentrate. Consequently, degrading water quality may threaten the economic viability of mining operations that make use of closed water circuits. Electrochemical techniques such as mineral rest potentials can be used to monitor the impact of changing water quality on collector–mineral interactions. Microflotation was used to determine whether mineral floatability was affected by changing water quality. This study therefore aimed to investigate whether electrochemical techniques such as rest potential measurements can be used to predict flotation performance under changing water quality. No definable relationship was found between the rest potential differences and the microflotation initial recoveries, however, rest potential measurements did identify the negative impact that thiosulphate ions may have on flotation processes.