Chloromethyl and methoxymethyl transition metal complexes : an investigation into their synthesis and reactivity

 

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dc.contributor.advisor Moss, John R en_ZA
dc.contributor.author Pelling, Simon en_ZA
dc.date.accessioned 2016-08-22T12:26:03Z
dc.date.available 2016-08-22T12:26:03Z
dc.date.issued 1981 en_ZA
dc.identifier.citation Pelling, S. 1981. Chloromethyl and methoxymethyl transition metal complexes : an investigation into their synthesis and reactivity. University of Cape Town. en_ZA
dc.identifier.uri http://hdl.handle.net/11427/21426
dc.description Bibliography: p. 125-129. en_ZA
dc.description.abstract Transition metal methoxymethyl and chloromethyl complexes may be versatile starting materials for the synthesis of several types of new complexes, including hydroxymethyl and carbene complexes, respectively [LₙMCH₂OH] and [LₙMCH₂]⁺ (M=transition metal, L=ligands). Hydroxymethyl and carbene transition metal complexes are models of catalytic intermediates in the Fischer-Tropsch reaction. We have synthesized the new chloromethyl complexes [Ru(Cp)(CO)₂CH₂CI], [Re(CO)₅CH₂CI], and cis-[Mn(CO)₄(PPh₃)CH₂CI], and the new methoxymethyl The existence of rotational isomerism in the complexes [Ru(Cp)(CO)₂CH₂ocH₃] and the previously reported [Fe(Cp)(CO)₂CH₂OCH₃],⁴⁸ is proposed on the basis of infrared data. Mass spectra of several methoxymethyl and chloromethyl transition metal complexes have been recorded. en_ZA
dc.language.iso eng en_ZA
dc.title Chloromethyl and methoxymethyl transition metal complexes : an investigation into their synthesis and reactivity en_ZA
dc.type Thesis / Dissertation en_ZA
uct.type.publication Research en_ZA
uct.type.resource Thesis en_ZA
dc.publisher.institution University of Cape Town
dc.publisher.faculty Faculty of Science en_ZA
dc.publisher.department Department of Chemistry en_ZA
dc.type.qualificationlevel Masters en_ZA
dc.type.qualificationname MSc en_ZA
uct.type.filetype Text
uct.type.filetype Image


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